Synthesis of Nitrogen-Containing Rubicene and Tetrabenzopentacene Derivatives
Dr. Young S. Park
Department of Chemical Engineering and Materials Science, University of California, Irvine, Irvine, CA, 92697 USA
These authors contributed equally to this work.
Search for more papers by this authorDr. David J. Dibble
Department of Chemical Engineering and Materials Science, University of California, Irvine, Irvine, CA, 92697 USA
These authors contributed equally to this work.
Search for more papers by this authorDr. Juhwan Kim
Department of Chemical Engineering and Materials Science, University of California, Irvine, Irvine, CA, 92697 USA
Search for more papers by this authorRobert C. Lopez
Department of Chemistry, University of California, Irvine, Irvine, CA, 92697 USA
Search for more papers by this authorEriberto Vargas
Department of Chemical Engineering and Materials Science, University of California, Irvine, Irvine, CA, 92697 USA
Search for more papers by this authorCorresponding Author
Prof. Alon A. Gorodetsky
Department of Chemical Engineering and Materials Science, University of California, Irvine, Irvine, CA, 92697 USA
Department of Chemistry, University of California, Irvine, Irvine, CA, 92697 USA
Search for more papers by this authorDr. Young S. Park
Department of Chemical Engineering and Materials Science, University of California, Irvine, Irvine, CA, 92697 USA
These authors contributed equally to this work.
Search for more papers by this authorDr. David J. Dibble
Department of Chemical Engineering and Materials Science, University of California, Irvine, Irvine, CA, 92697 USA
These authors contributed equally to this work.
Search for more papers by this authorDr. Juhwan Kim
Department of Chemical Engineering and Materials Science, University of California, Irvine, Irvine, CA, 92697 USA
Search for more papers by this authorRobert C. Lopez
Department of Chemistry, University of California, Irvine, Irvine, CA, 92697 USA
Search for more papers by this authorEriberto Vargas
Department of Chemical Engineering and Materials Science, University of California, Irvine, Irvine, CA, 92697 USA
Search for more papers by this authorCorresponding Author
Prof. Alon A. Gorodetsky
Department of Chemical Engineering and Materials Science, University of California, Irvine, Irvine, CA, 92697 USA
Department of Chemistry, University of California, Irvine, Irvine, CA, 92697 USA
Search for more papers by this authorAbstract
Carbon-based materials, such as acenes, fullerenes, and graphene nanoribbons, are viewed as the potential successors to silicon in the next generation of electronics. Although a number of methodologies provide access to these materials’ all-carbon variants, relatively fewer strategies readily furnish their nitrogen-doped analogues. Herein, we report the rational design, preparation, and characterization of nitrogen-containing rubicenes and tetrabenzopentacenes, which can be viewed either as acene derivatives or as molecular fragments of fullerenes and graphene nanoribbons. The reported findings may prove valuable for the development of electron transporting organic semiconductors and for the eventual construction of larger carbonaceous systems.
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