Large-Area, Free-Standing, Two-Dimensional Supramolecular Polymer Single-Layer Sheets for Highly Efficient Electrocatalytic Hydrogen Evolution
Dr. Renhao Dong
Department of Chemistry and Food Chemistry, and Center for Advancing Electronics Dresden, Technische Universität Dresden, 01062 Dresden (Germany)
Search for more papers by this authorMartin Pfeffermann
Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz (Germany)
Search for more papers by this authorDr. Haiwei Liang
Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz (Germany)
Search for more papers by this authorDr. Zhikun Zheng
Department of Chemistry and Food Chemistry, and Center for Advancing Electronics Dresden, Technische Universität Dresden, 01062 Dresden (Germany)
Search for more papers by this authorDr. Xiang Zhu
Department of Chemistry and Food Chemistry, and Center for Advancing Electronics Dresden, Technische Universität Dresden, 01062 Dresden (Germany)
Search for more papers by this authorDr. Jian Zhang
Department of Chemistry and Food Chemistry, and Center for Advancing Electronics Dresden, Technische Universität Dresden, 01062 Dresden (Germany)
Search for more papers by this authorCorresponding Author
Prof. Dr. Xinliang Feng
Department of Chemistry and Food Chemistry, and Center for Advancing Electronics Dresden, Technische Universität Dresden, 01062 Dresden (Germany)
Department of Chemistry and Food Chemistry, and Center for Advancing Electronics Dresden, Technische Universität Dresden, 01062 Dresden (Germany)Search for more papers by this authorDr. Renhao Dong
Department of Chemistry and Food Chemistry, and Center for Advancing Electronics Dresden, Technische Universität Dresden, 01062 Dresden (Germany)
Search for more papers by this authorMartin Pfeffermann
Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz (Germany)
Search for more papers by this authorDr. Haiwei Liang
Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz (Germany)
Search for more papers by this authorDr. Zhikun Zheng
Department of Chemistry and Food Chemistry, and Center for Advancing Electronics Dresden, Technische Universität Dresden, 01062 Dresden (Germany)
Search for more papers by this authorDr. Xiang Zhu
Department of Chemistry and Food Chemistry, and Center for Advancing Electronics Dresden, Technische Universität Dresden, 01062 Dresden (Germany)
Search for more papers by this authorDr. Jian Zhang
Department of Chemistry and Food Chemistry, and Center for Advancing Electronics Dresden, Technische Universität Dresden, 01062 Dresden (Germany)
Search for more papers by this authorCorresponding Author
Prof. Dr. Xinliang Feng
Department of Chemistry and Food Chemistry, and Center for Advancing Electronics Dresden, Technische Universität Dresden, 01062 Dresden (Germany)
Department of Chemistry and Food Chemistry, and Center for Advancing Electronics Dresden, Technische Universität Dresden, 01062 Dresden (Germany)Search for more papers by this authorAbstract
The rational construction of covalent or noncovalent organic two-dimensional nanosheets is a fascinating target because of their promising applications in electronics, membrane technology, catalysis, sensing, and energy technologies. Herein, a large-area (square millimeters) and free-standing 2D supramolecular polymer (2DSP) single-layer sheet (0.7–0.9 nm in thickness), comprising triphenylene-fused nickel bis(dithiolene) complexes has been readily prepared by using the Langmuir–Blodgett method. Such 2DSPs exhibit excellent electrocatalytic activities for hydrogen generation from water with a Tafel slope of 80.5 mV decade−1 and an overpotential of 333 mV at 10 mA cm−2, which are superior to that of recently reported carbon nanotube supported molecular catalysts and heteroatom-doped graphene catalysts. This work is promising for the development of novel free-standing organic 2D materials for energy technologies.
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