Metallocorroles as Photocatalysts for Driving Endergonic Reactions, Exemplified by Bromide to Bromine Conversion†
Dr. Atif Mahammed
Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Haifa 32000 (Israel)
Search for more papers by this authorCorresponding Author
Prof. Dr. Zeev Gross
Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Haifa 32000 (Israel)
Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Haifa 32000 (Israel)Search for more papers by this authorDr. Atif Mahammed
Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Haifa 32000 (Israel)
Search for more papers by this authorCorresponding Author
Prof. Dr. Zeev Gross
Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Haifa 32000 (Israel)
Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Haifa 32000 (Israel)Search for more papers by this authorThis research was supported by the Israel Science Foundation.
Abstract
Photochemical oxidation of halide anions by visible light has been suggested for solar energy conversion processes. Post-transition metallocorroles are now disclosed as very efficient catalysts for the photoinduced transformation of bromide to bromine. The advantages of these catalysts are that they are very stable under the reaction conditions and that the energy levels of the oxidizing HOMO and the reducing LUMO are easily tuned. Insights into the mechanism of action obtained in this work is predicted to be very useful for the design of other systems that rely on photocatalysis for driving endergonic reactions.
References
- 1
- 1aA. J. Bard, M. A. Fox, Acc. Chem. Res. 1995, 28, 141–145;
- 1bK. Maeda, J. Photochem. Photobiol. C 2011, 12, 237–268;
- 1cK. Maeda, K. Domen, J. Phys. Chem. Lett. 2010, 1, 2655–2661;
- 1dS. J. A. Moniz, S. A. Shevlin, D. J. Martin, Z.-X. Guo, J. Tang, Energy Environ. Sci. 2015, 8, 731–759.
- 2
- 2aK. Ohkubo, K. Mizushima, R. Iwata, S. Fukuzumi, Chem. Sci. 2011, 2, 715–722;
- 2bS. Fukuzumi, K. Ohkubo, T. Suenobu, Acc. Chem. Res. 2014, 47, 1455–1464;
- 2cJ. Palou, Chem. Soc. Rev. 1994, 23, 357–361;
- 2dL. S. Birnbaum, D. F. Staskal, Environ. Health Perspect. 2004, 112, 9–17;
- 2eR. Dabestani, X. Wang, A. J. Bard, A. Campion, M. A. Fox, S. E. Webber, J. M. White, J. Phys. Chem. 1986, 90, 2729–2732;
- 2fL. A. Tercero Espinoza, F. H. Frimmel, Water Res. 2008, 42, 1778–1784;
- 2gA. Slama-Schwok, S. Gershuni, J. Rabani, H. Cohen, D. Meyerstein, J. Phys. Chem. 1985, 89, 2460–2464.
- 3
- 3aV. Livshits, A. Ulus, E. Peled, Electrochem. Commun. 2006, 8, 1358–1362;
- 3bB. Huskinson, M. J. Aziz, Energy Sci. Technol. 2013, 5, 1–16.
- 4M. Kesner, Bromine and bromine compounds from the dead sea, Israel products in the service of people Weizmann Institute of Science the Ministry of Education and Dead Sea Bromine Group, 1999.
- 5
- 5aA. PodgorŠek, S. Stavber, M. Zupan, J. Iskra, Tetrahedron 2009, 65, 4429–4439;
- 5bW. J. Jones, Applications of Hydrogen Peroxide and Derivatives, Royal Society of Chemistry, Cambridge, 1999.
10.1039/9781847550132 Google Scholar
- 6
- 6aG. Knör, Chem. Phys. Lett. 2000, 330, 383–388;
- 6bT. Shiragami, J. Matsumoto, H. Inoue, M. Yasuda, J. Photochem. Photobiol. C 2005, 6, 227–248;
- 6cK. T. Oppelt, E. Wöß, M. Stiftinger, W. Schöfberger, W. Buchberger, G. Knör, Inorg. Chem. 2013, 52, 11910–11922;
- 6dW. Kim, J. Park, H. J. Jo, H.-J. Kim, W. Choi, J. Phys. Chem. C 2008, 112, 491–499;
- 6eG. Knör, Inorg. Chem. Commun. 2000, 3, 505–507.
- 7
- 7aL. Wagnert, A. Berg, E. Stavitski, T. Berthold, G. Kothe, I. Goldberg, A. Mahammed, L. Simkhovich, Z. Gross, H. Levanon, Appl. Magn. Reson. 2006, 30, 591–604;
- 7bC. M. Blumenfeld, R. H. Grubbs, R. A. Moats, H. B. Gray, K. Sorasaenee, Inorg. Chem. 2013, 52, 4774–4776.
- 8
- 8aJ. Y. Hwang, D. J. Lubow, J. D. Sims, H. B. Gray, A. Mahammed, Z. Gross, L. K. Medina-Kauwe, D. L. Farkas, J. Biomed. Opt. 2012, 17, 015003;
- 8bJ. Y. Hwang, D. J. Lubow, D. Chu, J. Sims, F. Alonso-Valenteen, H. B. Gray, Z. Gross, D. L. Farkas, L. K. Medina-Kauwe, J. Controlled Release 2012, 163, 368–373;
- 8cE. Stavitski, A. Berg, T. Ganguly, A. Mahammed, Z. Gross, H. Levanon, J. Am. Chem. Soc. 2004, 126, 6886–6890;
- 8dW. Shao, H. Wang, S. He, L. Shi, K. Peng, Y. Lin, L. Zhang, L. Ji, H. Liu, J. Phys. Chem. B 2012, 116, 14228–14234;
- 8eL. Flamigni, D. T. Gryko, Chem. Soc. Rev. 2009, 38, 1635–1646.
- 9
- 9aI. Luobeznova, M. Raizman, I. Goldberg, Z. Gross, Inorg. Chem. 2006, 45, 386–394;
- 9bL. Wagnert, A. Berg, E. Stavitski, I. Luobeznova, Z. Gross, H. Levanon, J. Porphyrins Phthalocyanines 2007, 11, 645–651.
- 10
- 10aA. Preuss, I. Saltsman, A. Mahammed, M. Pfitzner, I. Goldberg, Z. Gross, B. Roder, J. Photochem. Photobiol. B 2014, 133, 39–46;
- 10bJ. Pohl, I. Saltsman, A. Mahammed, Z. Gross, B. Roder, J. Appl. Microbiol. 2015, 118, 305–312;
- 10cX. Liang, J. Mack, L.-M. Zheng, Z. Shen, N. Kobayashi, Inorg. Chem. 2014, 53, 2797–2802;
- 10dA. Ghosh, M. Ravikanth, Chem. Eur. J. 2012, 18, 6386–6396;
- 10eL. Giribabu, J. Kandhadi, R. Kanaparthi, J. Fluoresc. 2014, 24, 569–577.
- 11L. Wagnert, R. Rubin, A. Berg, A. Mahammed, Z. Gross, H. Levanon, J. Phys. Chem. B 2010, 114, 14303–14308.
- 12A. I. Popov, R. F. Swensen, J. Am. Chem. Soc. 1955, 77, 3724–3726.
- 13A. Mahammed, B. Tumanskii, Z. Gross, J. Porphyrins Phthalocyanines 2011, 15, 1275–1286.
- 14A. B. Alemayehu, K. J. Gagnon, J. Terner, A. Ghosh, Angew. Chem. Int. Ed. 2014, 53, 14411–14414; Angew. Chem. 2014, 126, 14639–14642.
- 15A. Schechter, M. Stanevsky, A. Mahammed, Z. Gross, Inorg. Chem. 2012, 51, 22–24.
- 16
- 16aL. Simkhovich, A. Mahammed, I. Goldberg, Z. Gross, Chem. Eur. J. 2001, 7, 1041–1055;
10.1002/1521-3765(20010302)7:5<1041::AID-CHEM1041>3.0.CO;2-8 CAS PubMed Web of Science® Google Scholar
- 16bK. M. Kadish, Z. Ou, V. A. Adamian, R. Guilard, C. P. Gros, C. Erben, S. Will, E. Vogel, Inorg. Chem. 2000, 39, 5675–5682.
- 17P. S. Singh, D. H. Evans, J. Phys. Chem. B 2006, 110, 637–644.
- 18I. Rosenthal, A. Frimer, Photochem. Photobiol. 1976, 23, 209–211.
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