Actinide-Mediated Catalytic Addition of EH Bonds (E=N, P, S) to Carbodiimides, Isocyanates, and Isothiocyanates†
Isabell S. R. Karmel
Schulich Faculty of Chemistry, Technion—Israel Institute of Technology, Technion City, 32000 (Israel)
Search for more papers by this authorCorresponding Author
Matthias Tamm
Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, 38106 Braunschweig (Germany)
Matthias Tamm, Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, 38106 Braunschweig (Germany)
Moris S. Eisen, Schulich Faculty of Chemistry, Technion—Israel Institute of Technology, Technion City, 32000 (Israel)
Search for more papers by this authorCorresponding Author
Moris S. Eisen
Schulich Faculty of Chemistry, Technion—Israel Institute of Technology, Technion City, 32000 (Israel)
Matthias Tamm, Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, 38106 Braunschweig (Germany)
Moris S. Eisen, Schulich Faculty of Chemistry, Technion—Israel Institute of Technology, Technion City, 32000 (Israel)
Search for more papers by this authorIsabell S. R. Karmel
Schulich Faculty of Chemistry, Technion—Israel Institute of Technology, Technion City, 32000 (Israel)
Search for more papers by this authorCorresponding Author
Matthias Tamm
Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, 38106 Braunschweig (Germany)
Matthias Tamm, Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, 38106 Braunschweig (Germany)
Moris S. Eisen, Schulich Faculty of Chemistry, Technion—Israel Institute of Technology, Technion City, 32000 (Israel)
Search for more papers by this authorCorresponding Author
Moris S. Eisen
Schulich Faculty of Chemistry, Technion—Israel Institute of Technology, Technion City, 32000 (Israel)
Matthias Tamm, Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, 38106 Braunschweig (Germany)
Moris S. Eisen, Schulich Faculty of Chemistry, Technion—Israel Institute of Technology, Technion City, 32000 (Israel)
Search for more papers by this authorThis work was supported by the German Israel Foundation GIF under Contract I-1264-302.5/2014.
Abstract
Unprecedented catalytic reactivity of actinide coordination complexes toward heterocumulenes, such as carbodiimides, isocyanates, and isothiocyanates is reported. The mono(imidazolin-2-iminato) thorium(IV) complex [Th(ImDippN){N(SiMe3)2}3] (1) was applied as a precatalyst for the addition of EH (E=N, P, S) bonds to the YCX core (Y=R2N; X=NR2, O, S) of carbodiimides, isocyanates, and isothiocyanates. The respective insertion products were obtained in high yields under mild reaction conditions, with complex 1 displaying high tolerance toward functional groups and heteroatoms.
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