A Copper(I)–Arene Complex With an Unsupported η6 Interaction†
Dr. Ashley M. Wright
Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, CA 93106 (USA)
Search for more papers by this authorDr. Benjamin J. Irving
Department of Control Engineering, Faculty of Electrical Engineering, Czech Technical University in Prague, Karlovo náměstí 13, 121 35 Prague 2 (Czech Republic)
Search for more papers by this authorDr. Guang Wu
Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, CA 93106 (USA)
Search for more papers by this authorDr. Anthony J. H. M. Meijer
Department of Chemistry, University of Sheffield, Sheffield, S3 7HF (UK)
Search for more papers by this authorCorresponding Author
Prof. Dr. Trevor W. Hayton
Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, CA 93106 (USA)
Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, CA 93106 (USA)Search for more papers by this authorDr. Ashley M. Wright
Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, CA 93106 (USA)
Search for more papers by this authorDr. Benjamin J. Irving
Department of Control Engineering, Faculty of Electrical Engineering, Czech Technical University in Prague, Karlovo náměstí 13, 121 35 Prague 2 (Czech Republic)
Search for more papers by this authorDr. Guang Wu
Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, CA 93106 (USA)
Search for more papers by this authorDr. Anthony J. H. M. Meijer
Department of Chemistry, University of Sheffield, Sheffield, S3 7HF (UK)
Search for more papers by this authorCorresponding Author
Prof. Dr. Trevor W. Hayton
Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, CA 93106 (USA)
Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, CA 93106 (USA)Search for more papers by this authorResearch at UCSB was supported by the University of California, Santa Barbara and the National Science Foundation (CHE 1059097). This publication was also supported by the European social fund within the framework of the project “Support of inter-sectoral mobility and quality enhancement of research teams at Czech Technical University in Prague” (CZ.1.07/2.3.00/30.0034).
Abstract
Addition of PR3 (R=Ph or OPh) to [Cu(η2-Me6C6)2][PF6] results in the formation of [(η6-Me6C6)Cu(PR3)][PF6], the first copper–arene complexes to feature an unsupported η6 arene interaction. A DFT analysis reveals that the preference for the η6 binding mode is enforced by the steric clash between the methyl groups of the arene ligand and the phenyl rings of the phosphine co-ligand.
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