Turn-On Luminescence Sensing and Real-Time Detection of Traces of Water in Organic Solvents by a Flexible Metal–Organic Framework†
Antigoni Douvali
Department of Chemistry, University of Ioannina, 45110 Ioannina (Greece)
Search for more papers by this authorDr. Athanassios C. Tsipis
Department of Chemistry, University of Ioannina, 45110 Ioannina (Greece)
Search for more papers by this authorDr. Svetlana V. Eliseeva
Center of Molecular Biophysics, CNRS UPR 4301, Orleans (France)
Search for more papers by this authorProf. Stéphane Petoud
Center of Molecular Biophysics, CNRS UPR 4301, Orleans (France)
Search for more papers by this authorDr. Giannis S. Papaefstathiou
Department of Chemistry, National and Kapodistrian University of Athens, 15771 Zografou (Greece)
Search for more papers by this authorDr. Christos D. Malliakas
Department of Chemistry, Northwestern University, Evanston, IL 60208 (USA)
Search for more papers by this authorDr. Ioannis Papadas
Department of Materials Science and Technology, University of Crete, 71003 Heraklion (Greece)
Search for more papers by this authorDr. Gerasimos S. Armatas
Department of Materials Science and Technology, University of Crete, 71003 Heraklion (Greece)
Search for more papers by this authorDr. Irene Margiolaki
Department of Biology, University of Patras, 26500 Patras (Greece)
Search for more papers by this authorProf. Mercouri G. Kanatzidis
Department of Chemistry, Northwestern University, Evanston, IL 60208 (USA)
Search for more papers by this authorCorresponding Author
Dr. Theodore Lazarides
Department of Chemistry, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece)
Theodore Lazarides, Department of Chemistry, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece)
Manolis J. Manos, Department of Chemistry, University of Ioannina, 45110 Ioannina (Greece)
Search for more papers by this authorCorresponding Author
Dr. Manolis J. Manos
Department of Chemistry, University of Ioannina, 45110 Ioannina (Greece)
Theodore Lazarides, Department of Chemistry, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece)
Manolis J. Manos, Department of Chemistry, University of Ioannina, 45110 Ioannina (Greece)
Search for more papers by this authorAntigoni Douvali
Department of Chemistry, University of Ioannina, 45110 Ioannina (Greece)
Search for more papers by this authorDr. Athanassios C. Tsipis
Department of Chemistry, University of Ioannina, 45110 Ioannina (Greece)
Search for more papers by this authorDr. Svetlana V. Eliseeva
Center of Molecular Biophysics, CNRS UPR 4301, Orleans (France)
Search for more papers by this authorProf. Stéphane Petoud
Center of Molecular Biophysics, CNRS UPR 4301, Orleans (France)
Search for more papers by this authorDr. Giannis S. Papaefstathiou
Department of Chemistry, National and Kapodistrian University of Athens, 15771 Zografou (Greece)
Search for more papers by this authorDr. Christos D. Malliakas
Department of Chemistry, Northwestern University, Evanston, IL 60208 (USA)
Search for more papers by this authorDr. Ioannis Papadas
Department of Materials Science and Technology, University of Crete, 71003 Heraklion (Greece)
Search for more papers by this authorDr. Gerasimos S. Armatas
Department of Materials Science and Technology, University of Crete, 71003 Heraklion (Greece)
Search for more papers by this authorDr. Irene Margiolaki
Department of Biology, University of Patras, 26500 Patras (Greece)
Search for more papers by this authorProf. Mercouri G. Kanatzidis
Department of Chemistry, Northwestern University, Evanston, IL 60208 (USA)
Search for more papers by this authorCorresponding Author
Dr. Theodore Lazarides
Department of Chemistry, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece)
Theodore Lazarides, Department of Chemistry, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece)
Manolis J. Manos, Department of Chemistry, University of Ioannina, 45110 Ioannina (Greece)
Search for more papers by this authorCorresponding Author
Dr. Manolis J. Manos
Department of Chemistry, University of Ioannina, 45110 Ioannina (Greece)
Theodore Lazarides, Department of Chemistry, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece)
Manolis J. Manos, Department of Chemistry, University of Ioannina, 45110 Ioannina (Greece)
Search for more papers by this authorFinancial support from the National Science Foundation (Grant DMR-1410169) (MGK) and La Ligue Contre le Cancer, La Région Centre and the Institut National de la Santé et de la Recherche Médicale (SVE, SP) are gratefully acknowledged. The work in Center of Molecular Biophysics, France was carried out in the framework of European Cooperation in Science and Technology Actions TD1004 and CM1006. The variable-temperature diffraction measurements were carried out in the J. B. Cohen X-Ray Diffraction Facility supported by the MRSEC program of the National Science Foundation (DMR-1121262) at the Materials Research Center of Northwestern University. We would like also to thank the ESRF for provision of beam time at the ID22 beamline and Panalytical for the provision of the Xβ Pert Pro Lab diffractometer as well as F. Karavassili and Dr. A. Fitch for data collection at ID22 beamline. The National Strategic Reference Framework, Regional Operational Program of Epirus 2007-2013 (2011/S 29-048013), is acknowledged for supporting the purchase of an LS55 fluorimeter by the Department of Chemistry of the University of Ioannina.
Abstract
The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal–organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05–5 % v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.
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