Zuschrift

Synergetic Spin Crossover and Fluorescence in One-Dimensional Hybrid Complexes^†

Chun-Feng Wang

State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005 (China)

Search for more papers by this author

Dr. Ren-Fu Li,

Dr. Ren-Fu Li

Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)

Search for more papers by this author

Prof. Dr. Xue-Yuan Chen,

Prof. Dr. Xue-Yuan Chen

Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)

Search for more papers by this author

Dr. Rong-Jia Wei,

Dr. Rong-Jia Wei

State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005 (China)

Search for more papers by this author

Prof. Dr. Lan-Sun Zheng,

Prof. Dr. Lan-Sun Zheng

State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005 (China)

Search for more papers by this author

Prof. Dr. Jun Tao,

Corresponding Author

Prof. Dr. Jun Tao

[email protected]

State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005 (China)

State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005 (China)Search for more papers by this author

Chun-Feng Wang,

Chun-Feng Wang

State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005 (China)

Search for more papers by this author

Dr. Ren-Fu Li,

Dr. Ren-Fu Li

Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)

Search for more papers by this author

Prof. Dr. Xue-Yuan Chen,

Prof. Dr. Xue-Yuan Chen

Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)

Search for more papers by this author

Dr. Rong-Jia Wei,

Dr. Rong-Jia Wei

State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005 (China)

Search for more papers by this author

Prof. Dr. Lan-Sun Zheng,

Prof. Dr. Lan-Sun Zheng

State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005 (China)

Search for more papers by this author

Prof. Dr. Jun Tao,

Corresponding Author

Prof. Dr. Jun Tao

[email protected]

State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005 (China)

First published: 10 December 2014

https://doi.org/10.1002/ange.201410454

Citations: 29

^†

This work was supported by the National Natural Science Foundation of China (Grant 21325103), the National Basic Research Program of China (973 program, Grants 2014CB845601 and 2014CB845605), and the Specialized Research Fund for the Doctoral Program of Higher Education (Grant 20110121110012). X.Y.C. is grateful to the support from Special Project of National Major Scientific Equipment Development of China (2012YQ120060).

Share a link

Email
Wechat
Bluesky

Abstract

Hybrid materials integrated with a variety of physical properties, such as spin crossover (SCO) and fluorescence, may show synergetic effects that find applications in many fields. Herein we demonstrate a promising post-synthetic approach to achieve such materials by grafting fluorophores (1-pyrenecarboxaldehyde and Rhodamine B) on one-dimensional SCO Fe^II structures. The resulting hybrid materials display expected one-step SCO behavior and fluorescent properties, in particular showing a coupling between the transition temperature of SCO and the temperature where the fluorescent intensity reverses. Consequently, synergetic effect between SCO and fluorescence is incorporated into materials despite different fluorophores. This study provides an effective strategy for the design and development of novel magnetic and optical materials.

Supporting Information

References

1
1aP. D. Southon, L. Liu, E. A. Fellows, D. J. Price, G. J. Halder, K. W. Chapman, B. Moubaraki, K. S. Murray, J.-F. Létard, C. J. Kepert, J. Am. Chem. Soc. 2009, 131, 10998–11009;
10.1021/ja902187d
CAS PubMed Web of Science® Google Scholar
1bX. Bao, H. J. Shepherd, L. Salmon, G. Molnár, M.-L. Tong, A. Bousseksou, Angew. Chem. Int. Ed. 2013, 52, 1198–1202;
10.1002/anie.201207218
CAS PubMed Web of Science® Google Scholar
Angew. Chem. 2013, 125, 1236–1240;
10.1002/ange.201207218
Web of Science® Google Scholar
1cA. Bousseksou, G. Molnár, L. Salmon, W. Nicolazzi, Chem. Soc. Rev. 2011, 40, 3313–3335.
10.1039/c1cs15042a
CAS PubMed Web of Science® Google Scholar
2P. Gütlich, A. B. Gaspar, Y. Garcia, Beilstein J. Org. Chem. 2013, 9, 342–391.
10.3762/bjoc.9.39
CAS PubMed Web of Science® Google Scholar
3J. Linares, E. Codjovi, Y. Garcia, Sensors 2012, 12, 4479–4492.
10.3390/s120404479
CAS PubMed Web of Science® Google Scholar
4J. Tao, R.-J. Wei, R.-B. Huang, L.-S. Zheng, Chem. Soc. Rev. 2012, 41, 703–737.
10.1039/C1CS15136C
CAS PubMed Web of Science® Google Scholar
5
5aM. Matsuda, H. Isozaki, H. Tajima, Chem. Lett. 2008, 37, 374–375;
10.1246/cl.2008.374
CAS Web of Science® Google Scholar
5bM. Hasegawa, F. Renz, T. Hara, Y. Kikuchi, Y. Fukuda, J. Okubo, T. Hoshi, W. Linert, Chem. Phys. 2002, 277, 21–30;
10.1016/S0301-0104(01)00706-6
CAS Web of Science® Google Scholar
5cM. Engeser, L. Fabbrizzi, M. Licchelli, D. Sacchi, Chem. Commun. 1999, 1191–1192;
10.1039/a901931f
CAS Web of Science® Google Scholar
5dC. Edder, C. Piguet, J.-C. G. Bünzli, G. Hopfgartner, Chem. Eur. J. 2001, 7, 3014–3024;
10.1002/1521-3765(20010716)7:14<3014::AID-CHEM3014>3.0.CO;2-D
CAS PubMed Web of Science® Google Scholar
5eC. M. Quintero, I. A. Gural’skiy, L. Salmon, G. Molnár, B. Christian, A. Bousseksou, J. Mater. Chem. 2012, 22, 3745–3751.
10.1039/c2jm15662h
CAS Web of Science® Google Scholar
6L. Salmon, G. Molnar, D. Zitouni, C. Quintero, C. Bergaud, J.-C. Micheau, A. Bousseksou, J. Mater. Chem. 2010, 20, 5499–5503.
10.1039/c0jm00631a
CAS Web of Science® Google Scholar
7H. Matsukizono, K. Kuroiwa, N. Kimizuka, Chem. Lett. 2008, 37, 446–447.
10.1246/cl.2008.446
CAS Web of Science® Google Scholar
8Y. Garcia, F. Robert, A. D. Naik, G. Zhou, B. Tinant, K. Robeyns, S. Michotte, L. Piraux, J. Am. Chem. Soc. 2011, 133, 15850–15853.
10.1021/ja205974q
CAS PubMed Web of Science® Google Scholar
9
9aJ. Kröber, E. Codjovi, O. Kahn, F. Groliere, C. Jay, J. Am. Chem. Soc. 1993, 115, 9810–9811;
10.1021/ja00074a062
CAS Web of Science® Google Scholar
9bR. N. Muller, L. Vander Elst, S. Laurent, J. Am. Chem. Soc. 2003, 125, 8405–8407.
10.1021/ja0349599
CAS PubMed Web of Science® Google Scholar
10J. A. Carpenter, J. Dshemuchadse, S. Busato, I. Bräunlich, A. Pöthig, W. Caseri, Z. Anorg. Allg. Chem. 2014, 640, 724–732.
10.1002/zaac.201300605
CAS Web of Science® Google Scholar
11L. Zhang, G. Zhou, B. Sun, F. Chen, M. Zhao, T. Li, Macromol. Chem. Phys. 2013, 214, 1602–1611.
10.1002/macp.201300067
CAS Web of Science® Google Scholar
12
12aW. Xu, H. Guo, D. L. Akins, J. Phys. Chem. B 2001, 105, 1543–1546;
10.1021/jp003863n
CAS Web of Science® Google Scholar
12bC. Song, X. Zhang, C. Jia, P. Zhou, X. Quan, C. Duan, Talanta 2010, 81, 643–649;
10.1016/j.talanta.2009.12.047
CAS PubMed Web of Science® Google Scholar
12cV. Lykourinou, Y. Chen, X.-S. Wang, L. Meng, T. Hoang, L.-J. Ming, R. L. Musselman, S. Ma, J. Am. Chem. Soc. 2011, 133, 10382–10385;
10.1021/ja2038003
CAS PubMed Web of Science® Google Scholar
12dY. Chen, Q. Chen, L. Song, H.-P. Li, F.-Z. Hou, Microporous Mesoporous Mater. 2009, 122, 7–12.
10.1016/j.micromeso.2008.12.021
CAS Web of Science® Google Scholar
13S. Titos-Padilla, J. M. Herrera, X.-W. Chen, J. J. Delgado, E. Colacio, Angew. Chem. Int. Ed. 2011, 50, 3290–3293;
10.1002/anie.201007847
CAS PubMed Web of Science® Google Scholar
Angew. Chem. 2011, 123, 3348–3351.
10.1002/ange.201007847
Web of Science® Google Scholar
14
14aO. Kahn, J. Kröber, C. Jay, Adv. Mater. 1992, 4, 718–728;
10.1002/adma.19920041103
CAS Web of Science® Google Scholar
14bL. G. Lavrenova, V. N. Ikorskii, V. A. Varnek, I. M. Oglezneva, S. V. Larionov, Koord. Khim. 1990, 16, 654–661.
CAS Web of Science® Google Scholar
15
15aM. M. Dîrtu, C. Neuhausen, A. D. Naik, A. Rotaru, L. Spinu, Y. Garcia, Inorg. Chem. 2010, 49, 5723–5736;
10.1021/ic100667f
CAS PubMed Web of Science® Google Scholar
15bM. M. Dîrtu, A. Rotaru, D. Gillard, J. Linares, E. Codjovi, B. Tinant, Y. Garcia, Inorg. Chem. 2009, 48, 7838–7852.
10.1021/ic900814b
CAS PubMed Web of Science® Google Scholar
16M. Wen, K. Mori, T. Kamegawa, H. Yamashita, Chem. Commun. 2014, 50, 11645–11648.
10.1039/C4CC02994A
CAS PubMed Web of Science® Google Scholar

Citing Literature

Volume127, Issue5

January 26, 2015

Pages 1594-1597

This is the

German version

of Angewandte Chemie.

Note for articles published since 1962:

Do not cite this version alone.

Take me to the International Edition version with citable page numbers, DOI, and citation export.

We apologize for the inconvenience.

Synergetic Spin Crossover and Fluorescence in One-Dimensional Hybrid Complexes^†

Abstract

Supporting Information

References

Citing Literature

References

Information

About Wiley Online Library

Help & Support

Opportunities

Connect with Wiley

Synergetic Spin Crossover and Fluorescence in One-Dimensional Hybrid Complexes†

Abstract

Supporting Information

References

Citing Literature

References

Related

Information

Synergetic Spin Crossover and Fluorescence in One-Dimensional Hybrid Complexes^†