Electron-Transfer Photochromism To Switch Bulk Second-Order Nonlinear Optical Properties with High Contrast†
Dr. Pei-Xin Li
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Ming-Sheng Wang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)Search for more papers by this authorDr. Ming-Jian Zhang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)
Search for more papers by this authorDr. Chen-Sheng Lin
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)
Search for more papers by this authorLi-Zhen Cai
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)
Search for more papers by this authorSheng-Ping Guo
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Guo-Cong Guo
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)Search for more papers by this authorDr. Pei-Xin Li
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Ming-Sheng Wang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)Search for more papers by this authorDr. Ming-Jian Zhang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)
Search for more papers by this authorDr. Chen-Sheng Lin
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)
Search for more papers by this authorLi-Zhen Cai
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)
Search for more papers by this authorSheng-Ping Guo
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Guo-Cong Guo
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China)Search for more papers by this authorWe gratefully acknowledge financial support from the NSF of China (21373225, 21101152, 21221001, 91222204), 973 program (2011CBA00505), and the NSF of Fujian Province (2012J05032).
Abstract
The first bulk electron-transfer photochromic compound with intrinsic second-order nonlinear optical (NLO) photoswitching properties has been synthesized. This system employs an electron-transfer photoactive asymmetric viologen ligand coordinated to a zinc(II) center.
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