Highly Enantioselective Kinetic Resolution of Axially Chiral BINAM Derivatives Catalyzed by a Brønsted Acid†
Dr. Dao-Juan Cheng
Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Search for more papers by this authorLiang Yan
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Shi-Kai Tian
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026 (China)
Shi-Kai Tian, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026 (China)
Xin-Yuan Liu, Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Bin Tan, Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Search for more papers by this authorMing-Yue Wu
Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Search for more papers by this authorLu-Xin Wang
Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Search for more papers by this authorZi-Li Fan
Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Search for more papers by this authorDr. Sheng-Cai Zheng
Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Xin-Yuan Liu
Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Shi-Kai Tian, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026 (China)
Xin-Yuan Liu, Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Bin Tan, Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Bin Tan
Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Shi-Kai Tian, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026 (China)
Xin-Yuan Liu, Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Bin Tan, Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Search for more papers by this authorDr. Dao-Juan Cheng
Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Search for more papers by this authorLiang Yan
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Shi-Kai Tian
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026 (China)
Shi-Kai Tian, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026 (China)
Xin-Yuan Liu, Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Bin Tan, Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Search for more papers by this authorMing-Yue Wu
Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Search for more papers by this authorLu-Xin Wang
Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Search for more papers by this authorZi-Li Fan
Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Search for more papers by this authorDr. Sheng-Cai Zheng
Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Xin-Yuan Liu
Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Shi-Kai Tian, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026 (China)
Xin-Yuan Liu, Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Bin Tan, Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Bin Tan
Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Shi-Kai Tian, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026 (China)
Xin-Yuan Liu, Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Bin Tan, Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China)
Search for more papers by this authorFinancial support from the National Natural Science Foundation of China (Nos. 21232007, 21302088, 21302087), the National Basic Research Program of China (973 Program 2010CB833300), Shenzhen special funds for the development of biomedicine, Internet, new energy, and new material industries (JCYJ20130401144532131, JCYJ20130401144532137), and South University of Science and Technology of China is greatly appreciated.
Abstract
A highly efficient strategy for the kinetic resolution of axially chiral BINAM derivatives involving a chiral Brønsted acid-catalyzed imine formation and transfer hydrogenation cascade process was developed. The kinetic resolution provides a convenient route to chiral BINAM derivatives in high yields with excellent enantioselectivities.
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