Selective Janus Particle Assembly at Tipping Points of Thermally-Switched Wetting†
Changqian Yu
Department of Materials Science and Engineering, University of Illinois, Urbana, IL 61801 (USA) http://groups.mrl.uiuc.edu/granick/
Search for more papers by this authorJie Zhang
Department of Materials Science and Engineering, University of Illinois, Urbana, IL 61801 (USA) http://groups.mrl.uiuc.edu/granick/
Search for more papers by this authorCorresponding Author
Prof. Steve Granick
Department of Materials Science and Engineering, University of Illinois, Urbana, IL 61801 (USA) http://groups.mrl.uiuc.edu/granick/
Department of Chemistry, and Department of Physics, Urbana, IL 61801 (USA)
Department of Materials Science and Engineering, University of Illinois, Urbana, IL 61801 (USA) http://groups.mrl.uiuc.edu/granick/Search for more papers by this authorChangqian Yu
Department of Materials Science and Engineering, University of Illinois, Urbana, IL 61801 (USA) http://groups.mrl.uiuc.edu/granick/
Search for more papers by this authorJie Zhang
Department of Materials Science and Engineering, University of Illinois, Urbana, IL 61801 (USA) http://groups.mrl.uiuc.edu/granick/
Search for more papers by this authorCorresponding Author
Prof. Steve Granick
Department of Materials Science and Engineering, University of Illinois, Urbana, IL 61801 (USA) http://groups.mrl.uiuc.edu/granick/
Department of Chemistry, and Department of Physics, Urbana, IL 61801 (USA)
Department of Materials Science and Engineering, University of Illinois, Urbana, IL 61801 (USA) http://groups.mrl.uiuc.edu/granick/Search for more papers by this authorThis work as supported by the U.S. Army Research Office, Grant W911NF-10-1-0518.
Abstract
Thermal wetting can simply, selectively and reversibly join patchy particles into clusters (2D and 3D) and also colloidal crystals over the narrow temperature range of 1–2 °C. This is demonstrated with Janus particles (gold half-coated silica spheres) immersed in a binary mixture of water/2,6-lutidine, such that the relative strength of gold–gold bonding through hydrophobic interaction and silica–silica bonding through the wetting-induced attraction is reversibly switched according to temperature.
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References
- 1
- 1aQ. Chen, J. K. Whitmer, S. Jiang, S. C. Bae, E. Luijten, S. Granick, Science 2011, 331, 199–202;
- 1bP. F. Damasceno, M. Engel, S. C. Glotzer, Science 2012, 337, 453–457;
- 1cF. Li, D. P. Josephson, A. Stein, Angew. Chem. 2011, 123, 378–409; Angew. Chem. Int. Ed. 2011, 50, 360–388;
- 1dH. Pei, L. Liang, G. Yao, J. Li, Q. Huang, C. Fan, Angew. Chem. 2012, 124, 9154–9158; Angew. Chem. Int. Ed. 2012, 51, 9020–9024;
- 1eL. Phan, W. G. Walkup, D. D. Ordinario, E. Karshalev, J.-M. Jocson, A. M. Burke, A. A. Gorodetsky, Adv. Mater. 2013, 25, 5621–5625;
- 1fJ. S. Randhawa, T. G. Leong, N. Bassik, B. R. Benson, M. T. Jochmans, D. H. Gracias, J. Am. Chem. Soc. 2008, 130, 17238–17239;
- 1gS. Sacanna, L. Rossi, D. J. Pine, J. Am. Chem. Soc. 2012, 134, 6112–6115;
- 1hS. K. Y. Tang, R. Derda, A. D. Mazzeo, G. M. Whitesides, Adv. Mater. 2011, 23, 2413–2418.
- 2
- 2aM. D. McConnell, M. J. Kraeutler, S. Yang, R. J. Composto, Nano Lett. 2010, 10, 603–609;
- 2bO. D. Velev, E. W. Kaler, Langmuir 1999, 15, 3693–3698;
- 2cY. Zhang, F. Lu, D. van der Lelie, O. Gang, Phys. Rev. Lett. 2011, 107, 135701.
- 3
- 3aM. Y. Lin, S. K. Sinha, J. M. Drake, X. L. Wu, P. Thiyagarajan, H. B. Stanley, Phys. Rev. Lett. 1994, 72, 2207–2210;
- 3bD. W. Pohl, W. I. Goldburg, Phys. Rev. Lett. 1982, 48, 1111–1114.
- 4
- 4aU. Nellen, L. Helden, C. Bechinger, EPL 2009, 88, 26001;
- 4bF. Soyka, O. Zvyagolskaya, C. Hertlein, L. Helden, C. Bechinger, Phys. Rev. Lett. 2008, 101, 208301.
- 5C. A. Grattoni, R. A. Dawe, C. Y. Seah, J. D. Gray, J. Chem. Eng. Data 1993, 38, 516–519.
- 6
- 6aB. M. Law, J. M. Petit, D. Beysens, Phys. Rev. E 1998, 57, 5782–5794;
- 6bP. D. Gallagher, M. L. Kurnaz, J. V. Maher, Phys. Rev. A 1992, 46, 7750–7755.
- 7
- 7aD. Beysens, T. Narayanan, J. Stat. Phys. 1999, 95, 997–1008;
- 7bR. R. Netz, Phys. Rev. Lett. 1996, 76, 3646–3649.
- 8E. M. Herzig, K. A. White, A. B. Schofield, W. C. K. Poon, P. S. Clegg, Nat. Mater. 2007, 6, 966–971.
- 9V. Prasad, D. Semwogerere, E. R. Weeks, J. Phys. Condens. Matter 2007, 19, 113102.
- 10H. Shin, K. S. Schweizer, Soft Matter 2014, 10, 262–274.
- 11
- 11aA. Giacometti, F. Lado, J. Largo, G. Pastore, F. Sciortino, J. Chem. Phys. 2010, 132, 174110;
- 11bF. Sciortino, A. Giacometti, G. Pastore, Phys. Rev. Lett. 2009, 103, 237801.
- 12J. N. Israelachvili, Intermolecular and Surface Forces, revised 3rd ed., Academic Press, New York, 2011, pp. 538–559.
- 13V. N. Manoharan, M. T. Elsesser, D. J. Pine, Science 2003, 301, 483–487.
- 14D. Bonn, H. Kellay, G. H. Wegdam, Phys. Rev. Lett. 1992, 69, 1975–1978.
- 15W. L. Miller, A. Cacciuto, Phys. Rev. E 2009, 80, 021404.
- 16H.-J. Butt, M. Kappl, Adv. Colloid Interface Sci. 2009, 146, 48–60.
- 17Q. Chen, S. C. Bae, S. Granick, Nature 2011, 469, 381–384.
- 18Q. Chen, J. Yan, J. Zhang, S. C. Bae, S. Granick, Langmuir 2012, 28, 13555–13561.
- 19
- 19aM. E. Leunissen, R. Dreyfus, F. C. Cheong, D. G. Grier, R. Sha, N. C. Seeman, P. M. Chaikin, Nat. Mater. 2009, 8, 590–595;
- 19bM. M. Maye, M. T. Kumara, D. Nykypanchuk, W. B. Sherman, O. Gang, Nat. Nanotechnol. 2010, 5, 116–120;
- 19cF. Varrato, L. Di Michele, M. Belushkin, N. Dorsaz, S. H. Nathan, E. Eiser, G. Foffi, Proc. Natl. Acad. Sci. USA 2012, 109, 19155–19160.
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