Charge Asymmetry at Aqueous Hydrophobic Interfaces and Hydration Shells†
Dr. Rüdiger Scheu
Laboratory for fundamental BioPhotonics (LBP), Institute of Bioengineering (IBI), School of Engineering (STI), École Polytechnique Féderale de Lausanne (EPFL), 1015 Lausanne (Switzerland)
Search for more papers by this authorBlake M. Rankin
Purdue University, Department of Chemistry, West Lafayette, IN 47907 (USA)
Search for more papers by this authorYixing Chen
Laboratory for fundamental BioPhotonics (LBP), Institute of Bioengineering (IBI), School of Engineering (STI), École Polytechnique Féderale de Lausanne (EPFL), 1015 Lausanne (Switzerland)
Search for more papers by this authorDr. Kailash C. Jena
Laboratory for fundamental BioPhotonics (LBP), Institute of Bioengineering (IBI), School of Engineering (STI), École Polytechnique Féderale de Lausanne (EPFL), 1015 Lausanne (Switzerland)
Search for more papers by this authorProf. Dr. Dor Ben-Amotz
Purdue University, Department of Chemistry, West Lafayette, IN 47907 (USA)
Search for more papers by this authorCorresponding Author
Prof. Dr. Sylvie Roke
Laboratory for fundamental BioPhotonics (LBP), Institute of Bioengineering (IBI), School of Engineering (STI), École Polytechnique Féderale de Lausanne (EPFL), 1015 Lausanne (Switzerland)
Laboratory for fundamental BioPhotonics (LBP), Institute of Bioengineering (IBI), School of Engineering (STI), École Polytechnique Féderale de Lausanne (EPFL), 1015 Lausanne (Switzerland)Search for more papers by this authorDr. Rüdiger Scheu
Laboratory for fundamental BioPhotonics (LBP), Institute of Bioengineering (IBI), School of Engineering (STI), École Polytechnique Féderale de Lausanne (EPFL), 1015 Lausanne (Switzerland)
Search for more papers by this authorBlake M. Rankin
Purdue University, Department of Chemistry, West Lafayette, IN 47907 (USA)
Search for more papers by this authorYixing Chen
Laboratory for fundamental BioPhotonics (LBP), Institute of Bioengineering (IBI), School of Engineering (STI), École Polytechnique Féderale de Lausanne (EPFL), 1015 Lausanne (Switzerland)
Search for more papers by this authorDr. Kailash C. Jena
Laboratory for fundamental BioPhotonics (LBP), Institute of Bioengineering (IBI), School of Engineering (STI), École Polytechnique Féderale de Lausanne (EPFL), 1015 Lausanne (Switzerland)
Search for more papers by this authorProf. Dr. Dor Ben-Amotz
Purdue University, Department of Chemistry, West Lafayette, IN 47907 (USA)
Search for more papers by this authorCorresponding Author
Prof. Dr. Sylvie Roke
Laboratory for fundamental BioPhotonics (LBP), Institute of Bioengineering (IBI), School of Engineering (STI), École Polytechnique Féderale de Lausanne (EPFL), 1015 Lausanne (Switzerland)
Laboratory for fundamental BioPhotonics (LBP), Institute of Bioengineering (IBI), School of Engineering (STI), École Polytechnique Féderale de Lausanne (EPFL), 1015 Lausanne (Switzerland)Search for more papers by this authorThis work is supported by the Julia Jacobi Foundation, the Swiss National Science Foundation (grant number 200021_140472), the European Research Council (grant number 240556), the US National Science Foundation (CHE-1213338), and a PRF Research Grant from Purdue University. We thank John C. Conboy and Thomas L. Beck for useful discussions.
Graphical Abstract
Ladungsunterschiede: Wasser wird oft als dielektrisches Kontinuum modelliert, aber die molekulare Struktur von Wasser ist asymmetrisch. Zwei Ionen mit praktisch derselben Größe, Form und Struktur, aber entgegengesetzter Ladung wurden untersucht, um zu prüfen, ob Ladung die Wasserstrukturierung grundlegend beeinflusst. Die spektroskopischen Daten für die Hydratations- und Grenzflächenstrukturen erwiesen sich als bemerkenswert verschieden für entgegengesetzte Ladungen.
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