Dynamics of a Nanometer-Sized Uranyl Cluster in Solution†
Rene L. Johnson
Department of Chemistry, University of California, Davis, 1 Shields Ave, Davis, CA 95616 (USA)
Search for more papers by this authorCorresponding Author
Dr. C. André Ohlin
School of Chemistry, Monash University, Clayton, Victoria 3800 (Australia)
C. André Ohlin, School of Chemistry, Monash University, Clayton, Victoria 3800 (Australia)
William H. Casey, Department of Chemistry, University of California, Davis, 1 Shields Ave, Davis, CA 95616 (USA)
Search for more papers by this authorKristi Pellegrini
Department of Civil and Environmental Engineering and Earth Sciences, University of Notre Dame (USA)
Search for more papers by this authorProf. Peter C. Burns
Department of Civil and Environmental Engineering and Earth Sciences, University of Notre Dame (USA)
Department of Chemistry and Biochemistry, University of Notre Dame (USA)
Search for more papers by this authorCorresponding Author
Prof. William H. Casey
Department of Chemistry, University of California, Davis, 1 Shields Ave, Davis, CA 95616 (USA)
Department of Geology, University of California, Davis (USA)
C. André Ohlin, School of Chemistry, Monash University, Clayton, Victoria 3800 (Australia)
William H. Casey, Department of Chemistry, University of California, Davis, 1 Shields Ave, Davis, CA 95616 (USA)
Search for more papers by this authorRene L. Johnson
Department of Chemistry, University of California, Davis, 1 Shields Ave, Davis, CA 95616 (USA)
Search for more papers by this authorCorresponding Author
Dr. C. André Ohlin
School of Chemistry, Monash University, Clayton, Victoria 3800 (Australia)
C. André Ohlin, School of Chemistry, Monash University, Clayton, Victoria 3800 (Australia)
William H. Casey, Department of Chemistry, University of California, Davis, 1 Shields Ave, Davis, CA 95616 (USA)
Search for more papers by this authorKristi Pellegrini
Department of Civil and Environmental Engineering and Earth Sciences, University of Notre Dame (USA)
Search for more papers by this authorProf. Peter C. Burns
Department of Civil and Environmental Engineering and Earth Sciences, University of Notre Dame (USA)
Department of Chemistry and Biochemistry, University of Notre Dame (USA)
Search for more papers by this authorCorresponding Author
Prof. William H. Casey
Department of Chemistry, University of California, Davis, 1 Shields Ave, Davis, CA 95616 (USA)
Department of Geology, University of California, Davis (USA)
C. André Ohlin, School of Chemistry, Monash University, Clayton, Victoria 3800 (Australia)
William H. Casey, Department of Chemistry, University of California, Davis, 1 Shields Ave, Davis, CA 95616 (USA)
Search for more papers by this authorThis work is supported by the Office of Basic Energy Science of the U.S. Department of Energy as part of the Materials Science of Actinides Energy Frontier Research Center (DE-SC0001089). Additional funding sources are listed in the Supporting Information.
Graphical Abstract
Eine Klasse von Uranylperoxid-Clustern wurde früher als nanometergroße Ionen, die sich spontan in wässriger Lösung bilden, entdeckt. Der untersuchte Uranyl(VI)-Cluster hat einen Durchmesser von 2 nm und enthält 24 Uranyl- und 12 Phosphor-Einheiten. NMR-Spektroskopie zeigte, dass das Ion zwei Formen hat, die sich innerhalb von Millisekunden bis Sekunden ineinander umwandeln, abhängig von Temperatur und Größe der Gegenionen. P blau, O rot, U gelb.
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