Komplexe Formen und Dynamik von Dichlormethan-Tropfen†
Corresponding Author
Prof. Dr. Véronique Pimienta
UPS, IMRCP, Université de Toulouse, 118 route de Narbonne, 31062 Toulouse Cedex 9 (France)
Véronique Pimienta, UPS, IMRCP, Université de Toulouse, 118 route de Narbonne, 31062 Toulouse Cedex 9 (France)
Oliver Steinbock, Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306-4390 (USA)
Search for more papers by this authorDr. Michèle Brost
UPS, IMRCP, Université de Toulouse, 118 route de Narbonne, 31062 Toulouse Cedex 9 (France)
Search for more papers by this authorDr. Nina Kovalchuk
Institute of Biocolloid Chemistry, 42, Vernadsky av., 03142 Kiev (Ukraine)
Search for more papers by this authorStefan Bresch
Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306-4390 (USA)
Search for more papers by this authorCorresponding Author
Prof. Dr. Oliver Steinbock
Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306-4390 (USA)
Véronique Pimienta, UPS, IMRCP, Université de Toulouse, 118 route de Narbonne, 31062 Toulouse Cedex 9 (France)
Oliver Steinbock, Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306-4390 (USA)
Search for more papers by this authorCorresponding Author
Prof. Dr. Véronique Pimienta
UPS, IMRCP, Université de Toulouse, 118 route de Narbonne, 31062 Toulouse Cedex 9 (France)
Véronique Pimienta, UPS, IMRCP, Université de Toulouse, 118 route de Narbonne, 31062 Toulouse Cedex 9 (France)
Oliver Steinbock, Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306-4390 (USA)
Search for more papers by this authorDr. Michèle Brost
UPS, IMRCP, Université de Toulouse, 118 route de Narbonne, 31062 Toulouse Cedex 9 (France)
Search for more papers by this authorDr. Nina Kovalchuk
Institute of Biocolloid Chemistry, 42, Vernadsky av., 03142 Kiev (Ukraine)
Search for more papers by this authorStefan Bresch
Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306-4390 (USA)
Search for more papers by this authorCorresponding Author
Prof. Dr. Oliver Steinbock
Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306-4390 (USA)
Véronique Pimienta, UPS, IMRCP, Université de Toulouse, 118 route de Narbonne, 31062 Toulouse Cedex 9 (France)
Oliver Steinbock, Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306-4390 (USA)
Search for more papers by this authorWir danken David Villa (SPI-FR BT) für die Gegenlicht-Fotografie (Abbildungen 2 e,f und S1) und Jean-Claude Micheau für Diskussionen. Wir danken außerdem dem CNES und der UFR PCA der Université Paul Sabatier für die finanzielle Unterstützung. O.S. wird unterstützt von der National Science Foundation (Fördernr. CHE-0910657 und DMR-1005861).
Graphical Abstract
Die Erzeugung geordneter Bewegung durch chemische Prozesse wurde während der Solvatation mm-großer Tropfen aus CH2Cl2 in wässrigen Tensidlösungen beobachtet. Das System zeigt pulsierende Tropfen, mehrarmige Rotoren, und polygonale Formen. Die scharfen Spitzen dieser Muster stoßen kleinere Tröpfchen in Form expandierender Halos oder wirbelnder Ketten von sich. Die Tochtertröpfchen durchlaufen auch Kaskaden von Aufspaltungen zweiter und höherer Ordnung.
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