Single-Band Upconversion Emission in Lanthanide-Doped KMnF3 Nanocrystals†
Juan Wang
Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543 (Singapore)
Search for more papers by this authorDr. Feng Wang
Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543 (Singapore)
Search for more papers by this authorChao Wang
Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials, Soochow University, Suzhou, Jiangsu, 215123 (P.R. China)
Search for more papers by this authorProf. Zhuang Liu
Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials, Soochow University, Suzhou, Jiangsu, 215123 (P.R. China)
Search for more papers by this authorCorresponding Author
Prof. Xiaogang Liu
Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543 (Singapore)
Institute of Materials Research and Engineering, 3 Research Link, Singapore 117602 (Singapore)
Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543 (Singapore)Search for more papers by this authorJuan Wang
Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543 (Singapore)
Search for more papers by this authorDr. Feng Wang
Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543 (Singapore)
Search for more papers by this authorChao Wang
Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials, Soochow University, Suzhou, Jiangsu, 215123 (P.R. China)
Search for more papers by this authorProf. Zhuang Liu
Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials, Soochow University, Suzhou, Jiangsu, 215123 (P.R. China)
Search for more papers by this authorCorresponding Author
Prof. Xiaogang Liu
Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543 (Singapore)
Institute of Materials Research and Engineering, 3 Research Link, Singapore 117602 (Singapore)
Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543 (Singapore)Search for more papers by this authorThis study was supported in part by the Ministry of Education (MOE2010-T2-083), the Singapore–Peking–Oxford Research Enterprise (SPORE), and the Singapore–MIT alliance. We thank X. Huang and H. Zhu for their help in sample characterization.
Graphical Abstract
Klare Sicht: Das aufkonvertierte Emissionsspektrum von KMnF3-Nanokristallen, die mit Yb/Er (18:2 Mol-%; siehe Bild) oder Yb/Ho (18:2 Mol-%) dotiert sind, offenbart starke Einzelbandemissionen. Die Anwendung dieser unvermischten Emission für die Bildgebung von tiefliegendem Gewebe wird demonstriert.
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References
- 1
- 1aX. Xue, F. Wang, X. Liu, J. Mater. Chem. 2011, 21, 13107;
- 1bF. Wang, Y. Han, C. S. Lim, Y. H. Lu, J. Wang, J. Xu, H. Y. Chen, C. Zhang, M. Hong, X. Liu, Nature 2010, 463, 1061;
- 1cZ. Li, L. Li, H. Zhou, Q. Yuan, C. Chen, L. Sun, C. Yan, Chem. Commun. 2009, 6616;
- 1dC. Yan, A. Dadvand, F. Rosei, D. F. Perepichka, J. Am. Chem. Soc. 2010, 132, 8868;
- 1eN. Liu, W. Qin, G. Qin, T. Jiang, D. Zhao, Chem. Commun. 2011, 47, 7671;
- 1fH. Zhang, Y. Li, I. A. Ivanov, Y. Qu, Y. Huang, X. Duan, Angew. Chem. 2010, 122, 2927; Angew. Chem. Int. Ed. 2010, 49, 2865;
- 1gZ. Li, L. Wang, Z. Wang, X. Liu, Y. Xiong, J. Phys. Chem. C 2011, 115, 3291;
- 1hF. Zhang, G. B. Braun, Y. Shi, Y. Zhang, X. Sun, N. Reich, D. Zhao, G. Stucky, J. Am. Chem. Soc. 2010, 132, 2850;
- 1iS. Zhou, N. Jiang, K. Miura, S. Tanabe, M. Shimizu, M. Sakakura, Y. Shimotsuma, M. Nishi, J. Qiu, K. Hirao, J. Am. Chem. Soc. 2010, 132, 17945;
- 1jC. Jiang, F. Wang, N. Wu, X. Liu, Adv. Mater. 2008, 20, 4826.
- 2aA. Shalav, B. S. Richards, T. Trupke, K. W. Krämer, H. U. Güdel, Appl. Phys. Lett. 2005, 86, 013505;
- 2bA. Shalav, B. S. Richards, M. A. Green, Sol. Energy Mater. Sol. Cells 2007, 91, 829;
- 2cS. Ivanova, F. Pellé, J. Opt. Soc. Am. B 2009, 26, 1930;
- 2dB. M. van der Ende, L. Aarts. A. Meijerink, Phys. Chem. Chem. Phys. 2009, 11, 11081;
- 2eG. Wang, Q, Peng, Y. Li, Acc. Chem. Res. 2011, 44, 322.
- 3aM. Haase, H. Schäfer, Angew. Chem. 2011, 123, 5928;
10.1002/ange.201005159 Google ScholarAngew. Chem. Int. Ed. 2011, 50, 5808;
- 3bF. Wang, D. Banerjee, Y. Liu, X. Chen, X. Liu, Analyst 2010, 135, 1839;
- 3cH. S. Mader, P. Kele, S. M. Saleh, O. S. Wolfbeis, Curr. Opin. Chem. Biol. 2010, 14, 582;
- 3dJ. Shen, L. D. Sun, C. H. Yan, Dalton Trans. 2008, 5687;
- 3eZ. G. Chen, H. L. Chen, H. Hu, M. X. Yu, F. Y. Li, Q. Zhang, Z. G. Zhou, T. Yi, C. H. Huang, J. Am. Chem. Soc. 2008, 130, 3023;
- 3fM. Nyk, R. Kumar, T. Y. Ohulchanskyy, E. J. Bergey, P. N. Prasad, Nano Lett. 2008, 8, 3834;
- 3gG. K. Das, T. T. Y. Tan, J. Phys. Chem. C 2008, 112, 11211;
- 3hG. K. Das, B. C. Heng, S. C. Ng, T. White, J. S. C. Loo, L. D’Silva, P. Padmanabhan, K. K. Bhakoo, S. T. Selvan, T. T. Y. Tan, Langmuir 2010, 26, 8959;
- 3iG. Jia, H. You, K. Liu, Y. Zheng, N. Guo, H. Zhang, Langmuir 2010, 26, 5122;
- 3jG. Chen, T. Y. Ohulchanskyy, R. Kumar, H. Agren, P. N. Prasad, ACS Nano 2010, 4, 3163;
- 3kZ. Wang, J. Hao, H. L. W. Chan, G. L. Law, W. Wong, M. B. Murphy, T. Su, Z. Zhang, S. Zeng, Nanoscale 2011, 3, 2175;
- 3lP. Ghosh, J. Oliva, E. De La Rosa, K. K. Haldar, D. Solis, A. Patra, J. Phys. Chem. C 2008, 112, 9650;
- 3mH. Schäfer, P. Ptacek, K. Kömpe, M. Hasse, Chem. Mater. 2007, 19, 1396;
- 3nZ. Wang, J. Hao, H. L. W. Chan, J. Mater. Chem. 2010, 20, 3178;
- 3oJ. Hao, Y. Zhang, X. Wei, Angew. Chem. 2011, 123, 7008; Angew. Chem. Int. Ed. 2011, 50, 6876.
- 4
- 4aF. Wang, X. G. Liu, Chem. Soc. Rev. 2009, 38, 976;
- 4bS. Gai, P. Yang, C. Li, W. Wang, Y. Dai, N. Niu, J. Lin, Adv. Funct. Mater. 2010, 20, 1166;
- 4cQ. Liu, Y. Sun, C. Li, C. Li, J. Zhou, C. Li, T. Yang, X. Zhang, F. Li, ACS Nano 2011, 5, 3146;
- 4dH. S. Mader, O. S. Wolfbeis, Anal. Chem. 2010, 82, 5002;
- 4eD. Tu, L. Liu, Q. Ju, Y. Liu, H. Zhu, R. Li, X. Chen, Angew. Chem. 2011, 123, 6430; Angew. Chem. Int. Ed. 2011, 50, 6306;
- 4fH. Qian, H. Guo, P. Ho, R. Mahendran, Y. Zhang, Small 2009, 5, 2285;
- 4gN. M. Idris, Z. Q. Li, L. Ye, E. K. Sim, R. Mahendran, P. C. L. Ho, Y. Zhang, Biomaterials 2009, 30, 5104;
- 4hC. J. Carling, F. Nourmohammadian, J. C. Boyer, N. R. Branda, Angew. Chem. 2010, 122, 3870;
10.1002/ange.201000611 Google ScholarAngew. Chem. Int. Ed. 2010, 49, 3782;
- 4iRef. [3e];
- 4jT. Cao, Y. Yang, Y. Gao, J. Zhou, Z. Li, F. Li, Biomaterials 2011, 32, 2959;
- 4kJ. Zhou, M. Yu, Y. Sun, X. Zhang, X. Zhu, Z. Wu, D. Wu, F. Li, Biomaterials 2011, 32, 1148;
- 4lX. Yu, L. Chen, M. Li, M. Xie, L. Zhou, Y. Li, Q. Wang, Adv. Mater. 2008, 20, 4118;
- 4mC. Wang, L. Cheng, Z. Liu, Biomaterials 2011, 32, 1110;
- 4nC. Wang, H. Tao, L. Cheng, Z. Liu, Biomaterials 2011, 32, 6245;
- 4oL. H. Fischer, G. S. Harms, O. S. Wolfbeis, Angew. Chem. 2011, 123, 4640; Angew. Chem. Int. Ed. 2011, 50, 4546.
- 5
- 5aJ. Wang, F. Wang, J. Xu, Y. Wang, Y. Liu, X. Chen, H. Chen, X. Liu, C. R. Chim. 2010, 13, 731;
- 5bF. Wang, J. Wang, X. Liu, Angew. Chem. 2010, 122, 7618; Angew. Chem. Int. Ed. 2010, 49, 7456;
- 5cF. Wang, J. Wang, J. Xu, X. Xue, H. Chen, X. Liu, Spectrosc. Lett. 2010, 43, 400;
- 5dF. Heine, E. Heumann, T. Danger, T. Schweizer, G. Hüber, Appl. Phys. Lett. 1994, 65, 383;
- 5eT. Sandrock, H. Scheife, E. Heumann, G. Huber, Opt. Lett. 1997, 22, 808;
- 5fC. Chen, L. D. Sun, Z. X. Li, L. L. Li, J. Zhang, Y. W. Zhang, C. H. Yan, Langmuir 2010, 26, 8797;
- 5gF. Zhang, Y. Wan, T. Yu, F. Zhang, Y. Shi, S. Xie, Y. Li, L. Xu, B. Tu, D. Zhao, Angew. Chem. 2007, 119, 8122; Angew. Chem. Int. Ed. 2007, 46, 7976;
- 5hW. Niu, S. Wu, S. Zhang, J. Mater. Chem. 2010, 20, 9113;
- 5iG. Wang, Q. Peng, Y. Li, Chem. Eur. J. 2010, 16, 4923;
- 5jK. A. Abel, J. C. Boyer, F. C. J. M. van Veggel, J. Am. Chem. Soc. 2009, 131, 14644;
- 5kN. M. Sangeetha, F. C. J. M. van Veggel, J. Phys. Chem. C 2009, 113, 14702;
- 5lD. Q. Chen, Y. L. Yu, F. Huang, P. Huang, A. P. Yang, Y. S. Wang, J. Am. Chem. Soc. 2010, 132, 9976;
- 5mD. Q. Chen, Y. L. Yu, F. Huang, Y. S. Wang, Chem. Commun. 2011, 47, 2601;
- 5nJ. C. Boyer, L. A. Cuccia, J. A. Capobianco, Nano Lett. 2007, 7, 847;
- 5oJ. C. Boyer, J. Gagnon, L. A. Cuccia, J. A. Capobianco, Chem. Mater. 2007, 19, 3358;
- 5pV. Mahalingam, R. Naccache, F. Vetrone, J. A. Capobianco, Chem. Eur. J. 2009, 15, 9660;
- 5qG. S. Yi, G. M. Chow, Chem. Mater. 2007, 19, 341;
- 5rG. S. Yi, G. M. Chow, Adv. Funct. Mater. 2006, 16, 2324;
- 5sG. Yi, Y. Peng, Z. Gao, Chem. Mater. 2011, 23, 2729;
- 5tC. H. Liu, D. P. Chen, J. Mater. Chem. 2007, 17, 3875;
- 5uW. Niu, S. Wu, S. Zhang, L. Li, Chem. Commun. 2010, 46, 3908;
- 5vX. Ye, J. Collins, Y. Kang, J. Chen, D. T. N. Chen, A. G. Yodh, C. B. Murray, Proc. Natl. Acad. Sci. USA 2010, 107, 22430;
- 5wH. Q. Wang, T. Nann, ACS Nano 2010, 3, 3804.
- 6
- 6aG. Blasse, B. C. Grabmaier, Luminescent materials, Springer, Berlin, 1994;
10.1007/978-3-642-79017-1 Google Scholar
- 6bJ. F. Suyver, J. Grimm, K. W. Krämer, H. U. Güdel, J. Lumin. 2005, 114, 53;
- 6cG. He, P. P. Markowicz, T. Lin, P. N. Prasad, Nature 2002, 415, 767;
- 6dF. Auzel, Chem. Rev. 2004, 104, 139;
- 6eRef. [5t].
- 7W. Song, A. E. Vasdekis, Z. Li, D. Psaltis, Appl. Phys. Lett. 2009, 94, 051117.
- 8
- 8aF. Wang, X. Liu, J. Am. Chem. Soc. 2008, 130, 5642;
- 8bJ. Zhao, Y. Sun, X. Kong, L. Tian, Y. Wang, L. Tu, J. Zhao, H. Zhang, J. Phys. Chem. B 2008, 112, 15666.
- 9
- 9aM. Xie, X. Peng, X. Fu, J. Zhang, G. Li, X. Yu, Scr. Mater. 2009, 60, 190;
- 9bJ. Zeng, T. Xie, Z. Li, Y. Li, Cryst. Growth Des. 2007, 7, 2774;
- 9cD. D. Sell, R. L. Greene, R. M. White, Phys. Rev. 1967, 158, 489;
- 9dJ. M. Flaherty, B. D. Bartolo, J. Lumin. 1973, 8, 51.
- 10H. X. Mai, Y. W. Zhang, L. D. Sun, C. H. Yan, Chem. Mater. 2007, 19, 4514.
- 11
- 11aY. Vaills, J. Y. Buzare, M. Rousseau, J. Phys. Condens. Matter 1990, 2, 3997;
- 11bJ. L. Patel, J. J. Davies, B. C. Cavenett, J. Phys. C 1976, 9, 129.
- 12
- 12aK. König, J. Microsc. 2000, 200, 83;
- 12bR. G. Aswathy, Y. Yoshida, T. Maekawa, D. S. Kumar, Anal. Bioanal. Chem. 2010, 397, 1417.
- 13J. Park, K. An, Y. H, J. G. Park, H. J. Noh, J. Y. Kim, J. H. Park, N. M. Hwang, T. Hyeon, Nat. Mater. 2004, 3, 891.
- 14L. Cheng, K. Yang, S. Zhuang, M. W. Shao, S. T. Lee, Z. Liu, Nano Res. 2010, 3, 676.
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