Komplexe von N-heterocyclischen Carbenen mit Boranen: Synthese und Reaktionen†
Corresponding Author
Prof. Dennis P. Curran
Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA)
Dennis P. Curran, Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA)
Louis Fensterbank, UPMC Univ Paris 06, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), C. 229, 4 place Jussieu, 75005 Paris (Frankreich)
Emmanuel Lacôte, ICSN CNRS, Avenue de la Terrasse, 91198 Gif-sur-Yvette Cedex (Frankreich)
Search for more papers by this authorAndrey Solovyev
Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA)
Search for more papers by this authorDr. Malika Makhlouf Brahmi
UPMC Univ Paris 06, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), C. 229, 4 place Jussieu, 75005 Paris (Frankreich)
Search for more papers by this authorCorresponding Author
Prof. Louis Fensterbank
UPMC Univ Paris 06, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), C. 229, 4 place Jussieu, 75005 Paris (Frankreich)
Dennis P. Curran, Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA)
Louis Fensterbank, UPMC Univ Paris 06, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), C. 229, 4 place Jussieu, 75005 Paris (Frankreich)
Emmanuel Lacôte, ICSN CNRS, Avenue de la Terrasse, 91198 Gif-sur-Yvette Cedex (Frankreich)
Search for more papers by this authorProf. Max Malacria
UPMC Univ Paris 06, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), C. 229, 4 place Jussieu, 75005 Paris (Frankreich)
Search for more papers by this authorCorresponding Author
Dr. Emmanuel Lacôte
ICSN CNRS, Avenue de la Terrasse, 91198 Gif-sur-Yvette Cedex (Frankreich)
Dennis P. Curran, Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA)
Louis Fensterbank, UPMC Univ Paris 06, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), C. 229, 4 place Jussieu, 75005 Paris (Frankreich)
Emmanuel Lacôte, ICSN CNRS, Avenue de la Terrasse, 91198 Gif-sur-Yvette Cedex (Frankreich)
Search for more papers by this authorCorresponding Author
Prof. Dennis P. Curran
Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA)
Dennis P. Curran, Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA)
Louis Fensterbank, UPMC Univ Paris 06, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), C. 229, 4 place Jussieu, 75005 Paris (Frankreich)
Emmanuel Lacôte, ICSN CNRS, Avenue de la Terrasse, 91198 Gif-sur-Yvette Cedex (Frankreich)
Search for more papers by this authorAndrey Solovyev
Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA)
Search for more papers by this authorDr. Malika Makhlouf Brahmi
UPMC Univ Paris 06, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), C. 229, 4 place Jussieu, 75005 Paris (Frankreich)
Search for more papers by this authorCorresponding Author
Prof. Louis Fensterbank
UPMC Univ Paris 06, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), C. 229, 4 place Jussieu, 75005 Paris (Frankreich)
Dennis P. Curran, Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA)
Louis Fensterbank, UPMC Univ Paris 06, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), C. 229, 4 place Jussieu, 75005 Paris (Frankreich)
Emmanuel Lacôte, ICSN CNRS, Avenue de la Terrasse, 91198 Gif-sur-Yvette Cedex (Frankreich)
Search for more papers by this authorProf. Max Malacria
UPMC Univ Paris 06, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), C. 229, 4 place Jussieu, 75005 Paris (Frankreich)
Search for more papers by this authorCorresponding Author
Dr. Emmanuel Lacôte
ICSN CNRS, Avenue de la Terrasse, 91198 Gif-sur-Yvette Cedex (Frankreich)
Dennis P. Curran, Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA)
Louis Fensterbank, UPMC Univ Paris 06, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), C. 229, 4 place Jussieu, 75005 Paris (Frankreich)
Emmanuel Lacôte, ICSN CNRS, Avenue de la Terrasse, 91198 Gif-sur-Yvette Cedex (Frankreich)
Search for more papers by this authorDer Vortitel basiert auf einer Fotografie der Pferde von Marly. Copyright Marie-Lan Nguyen, Wikimedia Commons.
Abstract
Borane sind weit verbreitete Lewis-Säuren, und N-heterocyclische Carbene (NHCs) sind beliebte Lewis-Basen. Dennoch war bis in die jüngste Zeit erstaunlich wenig über Komplexe dieser beiden Verbindungsklassen miteinander bekannt. NHC-Borane sind leicht herzustellen, und teilweise sind sie so stabil, dass sie weniger als Komplex, sondern vielmehr als eigenständige organische Verbindung betrachtet werden können. Sie verhalten sich nicht wie klassische Borane, und sie können ein breites Spektrum an funktionellen Gruppen enthalten. Als vielseitige Reaktionspartner, Reagentien und Katalysatoren verfügen NHC-Borane über ein immenses Potenzial für die organische Synthese und die Polymerchemie. Viele Reaktionen von NHC-Boranen laufen über neue reaktive Intermediate wie Boreniumkationen, Borylradikale und sogar Borylanionen ab. Hier geben wir eine umfassende Übersicht über die Synthese, Charakterisierung und Reaktionen von NHC-Boranen.
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