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Über die Quecksilberbrücke – ein Weg zu einem Diwasserstoffcobaltkomplex^†

Corresponding Author

Dr. R. Morris Bullock

[email protected]

Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Richland, WA 99352 (USA) http://efrc.pnl.gov/

Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Richland, WA 99352 (USA) http://efrc.pnl.gov/Search for more papers by this author

Dr. R. Morris Bullock,

Corresponding Author

Dr. R. Morris Bullock

[email protected]

Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Richland, WA 99352 (USA) http://efrc.pnl.gov/

Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Richland, WA 99352 (USA) http://efrc.pnl.gov/Search for more papers by this author

First published: 30 March 2011

https://doi.org/10.1002/ange.201006731

^†

R.M.B. dankt dem U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Biosciences and Geosciences für finanzielle Unterstützung. Das Pacific Northwest National Laboratory wird von Battelle für das U.S. Department of Energy betrieben.

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Graphical Abstract

Zwei H₂: Quecksilber schützt das hoch reaktive 14-Elektronen-Fragment {Co(POCOP)} in einem Co-Hg-Co-Komplex, doch die Reaktion mit H₂ führt zu einem seltenen Diwasserstoffkomplex von Cobalt, der ein zweites H₂-Molekül unter hohem Druck und bei tiefer Temperatur aufnehmen kann (siehe Schema).

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Volume123, Issue18

April 26, 2011

Pages 4136-4138

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Über die Quecksilberbrücke – ein Weg zu einem Diwasserstoffcobaltkomplex^†

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Über die Quecksilberbrücke – ein Weg zu einem Diwasserstoffcobaltkomplex†

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Über die Quecksilberbrücke – ein Weg zu einem Diwasserstoffcobaltkomplex^†