Innentitelbild: Generation and Reactions of an Unsubstituted N-Heterocyclic Carbene Boryl Anion (Angew. Chem. 48/2010)
Dr. Julien Monot
Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA), Fax: (+1) 412-624-9861
Search for more papers by this authorAndrey Solovyev
Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA), Fax: (+1) 412-624-9861
Search for more papers by this authorDr. Hélène Bonin-Dubarle
Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Search for more papers by this authorDr. Étienne Derat
Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Search for more papers by this authorCorresponding Author
Prof. Dennis P. Curran
Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA), Fax: (+1) 412-624-9861
Dennis P. Curran, Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA), Fax: (+1) 412-624-9861
Louis Fensterbank, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Max Malacria, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Emmanuel Lacôte, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Search for more papers by this authorProf. Marc Robert
Laboratoire d'Electrochimie Moléculaire (UMR CNRS 7591), Université Paris Diderot, 75013 Paris (France)
Search for more papers by this authorCorresponding Author
Prof. Louis Fensterbank
Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Dennis P. Curran, Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA), Fax: (+1) 412-624-9861
Louis Fensterbank, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Max Malacria, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Emmanuel Lacôte, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Search for more papers by this authorCorresponding Author
Prof. Max Malacria
Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Dennis P. Curran, Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA), Fax: (+1) 412-624-9861
Louis Fensterbank, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Max Malacria, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Emmanuel Lacôte, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Search for more papers by this authorCorresponding Author
Dr. Emmanuel Lacôte
Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Dennis P. Curran, Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA), Fax: (+1) 412-624-9861
Louis Fensterbank, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Max Malacria, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Emmanuel Lacôte, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Search for more papers by this authorDr. Julien Monot
Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA), Fax: (+1) 412-624-9861
Search for more papers by this authorAndrey Solovyev
Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA), Fax: (+1) 412-624-9861
Search for more papers by this authorDr. Hélène Bonin-Dubarle
Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Search for more papers by this authorDr. Étienne Derat
Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Search for more papers by this authorCorresponding Author
Prof. Dennis P. Curran
Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA), Fax: (+1) 412-624-9861
Dennis P. Curran, Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA), Fax: (+1) 412-624-9861
Louis Fensterbank, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Max Malacria, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Emmanuel Lacôte, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Search for more papers by this authorProf. Marc Robert
Laboratoire d'Electrochimie Moléculaire (UMR CNRS 7591), Université Paris Diderot, 75013 Paris (France)
Search for more papers by this authorCorresponding Author
Prof. Louis Fensterbank
Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Dennis P. Curran, Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA), Fax: (+1) 412-624-9861
Louis Fensterbank, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Max Malacria, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Emmanuel Lacôte, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Search for more papers by this authorCorresponding Author
Prof. Max Malacria
Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Dennis P. Curran, Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA), Fax: (+1) 412-624-9861
Louis Fensterbank, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Max Malacria, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Emmanuel Lacôte, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Search for more papers by this authorCorresponding Author
Dr. Emmanuel Lacôte
Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Dennis P. Curran, Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 (USA), Fax: (+1) 412-624-9861
Louis Fensterbank, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Max Malacria, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Emmanuel Lacôte, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris (France), Fax: (+33) 1-4427-7360
Search for more papers by this authorGraphical Abstract
Leicht gemacht:Das gilt für die Synthese eines neuen Carbenborylanions, die in Kooperation von drei Gruppen in Paris und Pittsburgh entwickelt wurde. In ihrer Zuschift auf S. 9352 ff. weisen M. Malacria, D. P. Curran et al. den Weg zu einem Boryl-Anion mit koordiniertem N-heterocyclischen Carben über die reduktive Lithiierung eines Boryliodids. Das borzentrierte Anion lässt sich mit verschiedenartigen Elektrophilen unter Bildung ungewöhnlicher Carbenborane abfangen.
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