Towards Selective Ethylene Tetramerization†
Dr. Sebastiano Licciulli
Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5 (Canada), Fax: (+1) 613-562-5170
Search for more papers by this authorIndira Thapa
Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5 (Canada), Fax: (+1) 613-562-5170
Search for more papers by this authorKhalid Albahily
Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5 (Canada), Fax: (+1) 613-562-5170
Search for more papers by this authorDr. Ilia Korobkov
Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5 (Canada), Fax: (+1) 613-562-5170
Search for more papers by this authorCorresponding Author
Prof. Dr. Sandro Gambarotta
Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5 (Canada), Fax: (+1) 613-562-5170
Sandro Gambarotta, Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5 (Canada), Fax: (+1) 613-562-5170
Robbert Duchateau, Department of Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (The Netherlands)
Search for more papers by this authorCorresponding Author
Dr. Robbert Duchateau
Department of Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (The Netherlands)
Sandro Gambarotta, Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5 (Canada), Fax: (+1) 613-562-5170
Robbert Duchateau, Department of Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (The Netherlands)
Search for more papers by this authorDr. Reynald Chevalier
Lyondellbasell Industries, Polyolefine GmbH, Industriepark Hoechst, 65926 Frankfurt (Germany)
Search for more papers by this authorDr. Katrin Schuhen
Lyondellbasell Industries, Polyolefine GmbH, Industriepark Hoechst, 65926 Frankfurt (Germany)
Search for more papers by this authorDr. Sebastiano Licciulli
Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5 (Canada), Fax: (+1) 613-562-5170
Search for more papers by this authorIndira Thapa
Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5 (Canada), Fax: (+1) 613-562-5170
Search for more papers by this authorKhalid Albahily
Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5 (Canada), Fax: (+1) 613-562-5170
Search for more papers by this authorDr. Ilia Korobkov
Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5 (Canada), Fax: (+1) 613-562-5170
Search for more papers by this authorCorresponding Author
Prof. Dr. Sandro Gambarotta
Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5 (Canada), Fax: (+1) 613-562-5170
Sandro Gambarotta, Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5 (Canada), Fax: (+1) 613-562-5170
Robbert Duchateau, Department of Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (The Netherlands)
Search for more papers by this authorCorresponding Author
Dr. Robbert Duchateau
Department of Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (The Netherlands)
Sandro Gambarotta, Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5 (Canada), Fax: (+1) 613-562-5170
Robbert Duchateau, Department of Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (The Netherlands)
Search for more papers by this authorDr. Reynald Chevalier
Lyondellbasell Industries, Polyolefine GmbH, Industriepark Hoechst, 65926 Frankfurt (Germany)
Search for more papers by this authorDr. Katrin Schuhen
Lyondellbasell Industries, Polyolefine GmbH, Industriepark Hoechst, 65926 Frankfurt (Germany)
Search for more papers by this authorThis research was supported by the Natural Science and Engineering Council of Canada (NSERC), by the Eindhoven University of Technology, and by LyondellBasell.
Graphical Abstract
Und die magische Zahl ist …︁ 4! Eine große Menge an oligomerfreiem 1-Octen (99.9 %) wurde aus Ethylen bei der Bildung von Polyethylenwachs mithilfe eines Chromkatalysators erhalten (siehe GC-MS-Chromatogramm; die drei weiteren wesentlichen Signale stammen von Methanol (zum Abbrechen der Reaktion), Ethylacetat (Nadelreinigungsmittel) und Toluol (Solvens)).
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