Probing the Mechanism of Olefin Metathesis in Grubbs–Hoveyda and Grela Type Complexes†
Tim Vorfalt Dipl.-Ing.
Organometallic Chemistry, Technische Universität Darmstadt, Petersenstrasse 18, 64287 Darmstadt (Germany)
Search for more papers by this authorKlaus-Jürgen Wannowius Dr.
Organometallic Chemistry, Technische Universität Darmstadt, Petersenstrasse 18, 64287 Darmstadt (Germany)
Search for more papers by this authorHerbert Plenio Prof. Dr.
Organometallic Chemistry, Technische Universität Darmstadt, Petersenstrasse 18, 64287 Darmstadt (Germany)
Search for more papers by this authorTim Vorfalt Dipl.-Ing.
Organometallic Chemistry, Technische Universität Darmstadt, Petersenstrasse 18, 64287 Darmstadt (Germany)
Search for more papers by this authorKlaus-Jürgen Wannowius Dr.
Organometallic Chemistry, Technische Universität Darmstadt, Petersenstrasse 18, 64287 Darmstadt (Germany)
Search for more papers by this authorHerbert Plenio Prof. Dr.
Organometallic Chemistry, Technische Universität Darmstadt, Petersenstrasse 18, 64287 Darmstadt (Germany)
Search for more papers by this authorThis work was supported by the DFG via Pl 178/8-3.
Graphical Abstract
Je mehr, desto besser: Kinetische Daten aus UV/Vis-Messungen liefern schlüssige Hinweise für die Beteiligung des olefinischen Substrats am geschwindigkeitsbestimmenden Schritt der Initiierungsreaktion von Olefinmetathesekatalysatoren vom Grubbs-Hoveyda-Typ sowie für einen zweiten, Olefin-unabhängigen Schritt, der nur bei sehr hohen Olefinkonzentrationen geschwindigkeitsbestimmend wird.
Supporting Information
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