Volume 121, Issue 51 pp. 9870-9872

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Palladium-Catalyzed Intramolecular Carboesterification of Olefins^†

Yang Li Dr.,

Yang Li Dr.

Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139-4307 (USA)

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Katherine J. Jardine,

Katherine J. Jardine

Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, ON, M5S 3H6 (Canada)

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Runyu Tan,

Runyu Tan

Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, ON, M5S 3H6 (Canada)

To whom correspondence about crystallographic data should be addressed.

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Datong Song Prof.,

Datong Song Prof.

[email protected]

Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, ON, M5S 3H6 (Canada)

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Vy M. Dong Prof.,

Vy M. Dong Prof.

[email protected]

Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, ON, M5S 3H6 (Canada)

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Yang Li Dr.,

Yang Li Dr.

Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139-4307 (USA)

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Katherine J. Jardine,

Katherine J. Jardine

Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, ON, M5S 3H6 (Canada)

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Runyu Tan,

Runyu Tan

Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, ON, M5S 3H6 (Canada)

To whom correspondence about crystallographic data should be addressed.

Search for more papers by this author

Datong Song Prof.,

Datong Song Prof.

[email protected]

Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, ON, M5S 3H6 (Canada)

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Vy M. Dong Prof.,

Vy M. Dong Prof.

[email protected]

Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, ON, M5S 3H6 (Canada)

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First published: 08 December 2009

https://doi.org/10.1002/ange.200905478

Citations: 14

^†

We thank the University of Toronto, Canadian Foundation for Innovation, Ontario Ministry of Research and Innovation, and Natural Sciences and Engineering Research Council (NSERC) of Canada for funding. K.J.J. and R.T are grateful for NSERC and Ontario Graduate fellowships, respectively. Dr. Xiaodan Zhao and Prof. Shannon Stahl are thanked for helpful discussions.

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Graphical Abstract

Ein Katalysator, drei Bindungen: Die Titelreaktion zwischen Propiolsäuren und nichtaktivierten Olefinen (siehe Schema; O rot, Cl grün) führt unter Bildung neuer C-C- und C-O-Bindungen zur vicinalen Funktionalisierung des Olefins. Strukturell komplexe tricyclische 6,7,5-Ringsysteme entstehen bei dieser Kaskade aus Chloropalladierung und formaler [3+2]-Cycloaddition in einem Schritt.

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References

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Volume121, Issue51

December 14, 2009

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Palladium-Catalyzed Intramolecular Carboesterification of Olefins^†