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Spectroscopic Elucidation of First Steps of Supported Bimetallic Cluster Formation^†

Apoorva Kulkarni

Department of Chemical Engineering and Materials Science, University of California, One Shields Avenue, Davis, CA 95616 (USA), Fax: (+1) 530-752-1031 http://www.chms.ucdavis.edu/research/web/catalysis

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Bruce C. Gates Prof.,

Bruce C. Gates Prof.

[email protected]

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Apoorva Kulkarni,

Apoorva Kulkarni

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Bruce C. Gates Prof.,

Bruce C. Gates Prof.

[email protected]

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First published: 08 December 2009

https://doi.org/10.1002/ange.200904877

Citations: 5

^†

This work was supported by the National Science Foundation, GOALI Grant CTS-05-00511, and ExxonMobil. We acknowledge beam time and support of the DOE Division of Materials Sciences for its role in the operation and development of beam line MR-CAT at the Advanced Photon Source at Argonne National Laboratory.

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Graphical Abstract

Die ersten Stufen der Bildung von Ru-Os-Clustern auf einer MgO-Oberfläche in Gegenwart von H₂ wurden anhand von EXAFS- und IR-Spektren analysiert. Der Bildung der Ru-Os-Bindungen geht die Decarbonylierung von Ru₃- und dann, bei höheren Temperaturen, von Os₃-Clustern voraus (siehe Schema).

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Volume121, Issue51

December 14, 2009

Pages 9877-9880

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Spectroscopic Elucidation of First Steps of Supported Bimetallic Cluster Formation^†

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Spectroscopic Elucidation of First Steps of Supported Bimetallic Cluster Formation†

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Spectroscopic Elucidation of First Steps of Supported Bimetallic Cluster Formation^†