Unusual Interlocking and Interpenetration Lead to Highly Porous and Robust Metal–Organic Frameworks†
Liqing Ma Dr.
Department of Chemistry, CB no. 3290, University of North Carolina, Chapel Hill, NC 27599 (USA), Fax: (+1) 919-962-2388, http://www.chem.unc.edu/people/faculty/linw/wlindex.html
Search for more papers by this authorWenbin Lin Prof.
Department of Chemistry, CB no. 3290, University of North Carolina, Chapel Hill, NC 27599 (USA), Fax: (+1) 919-962-2388, http://www.chem.unc.edu/people/faculty/linw/wlindex.html
Search for more papers by this authorLiqing Ma Dr.
Department of Chemistry, CB no. 3290, University of North Carolina, Chapel Hill, NC 27599 (USA), Fax: (+1) 919-962-2388, http://www.chem.unc.edu/people/faculty/linw/wlindex.html
Search for more papers by this authorWenbin Lin Prof.
Department of Chemistry, CB no. 3290, University of North Carolina, Chapel Hill, NC 27599 (USA), Fax: (+1) 919-962-2388, http://www.chem.unc.edu/people/faculty/linw/wlindex.html
Search for more papers by this authorWe acknowledge financial support from NSF.
Abstract
Schluss mit Atmen: MOFs mit komplexen und großen organischen Brückenliganden neigen beim Entfernen des Lösungsmittels zu Gerüstverzerrungen („Atmen“). Ein Versteifen von MOFs mit langen Tetracarboxylat-Brückenliganden durch ein ungewöhnliches Verzahnen und Durchdringen liefert hoch poröse und robuste Hybridmaterialien.
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