Cooperative Ion–Ion Interactions in the Formation of Interpenetrated Molecules†
Dennis J. Hoffart
Department of Chemistry and Biochemistry, University of Windsor, Windsor, ON, N9B 3P4, Canada, Fax: (+1) 519-973-7098
Search for more papers by this authorJorge Tiburcio Dr.
Departamento de Química, Centro de Investigación y de Estudios Avanzados, Zacatenco, 07360, México, D.F., México, Fax: (+52) 55-5061-3389
Search for more papers by this authorAna de la Torre
Department of Chemistry and Biochemistry, University of Windsor, Windsor, ON, N9B 3P4, Canada, Fax: (+1) 519-973-7098
Search for more papers by this authorLisa K. Knight Dr.
Department of Chemistry and Biochemistry, University of Windsor, Windsor, ON, N9B 3P4, Canada, Fax: (+1) 519-973-7098
Search for more papers by this authorStephen J. Loeb Prof.
Department of Chemistry and Biochemistry, University of Windsor, Windsor, ON, N9B 3P4, Canada, Fax: (+1) 519-973-7098
Search for more papers by this authorDennis J. Hoffart
Department of Chemistry and Biochemistry, University of Windsor, Windsor, ON, N9B 3P4, Canada, Fax: (+1) 519-973-7098
Search for more papers by this authorJorge Tiburcio Dr.
Departamento de Química, Centro de Investigación y de Estudios Avanzados, Zacatenco, 07360, México, D.F., México, Fax: (+52) 55-5061-3389
Search for more papers by this authorAna de la Torre
Department of Chemistry and Biochemistry, University of Windsor, Windsor, ON, N9B 3P4, Canada, Fax: (+1) 519-973-7098
Search for more papers by this authorLisa K. Knight Dr.
Department of Chemistry and Biochemistry, University of Windsor, Windsor, ON, N9B 3P4, Canada, Fax: (+1) 519-973-7098
Search for more papers by this authorStephen J. Loeb Prof.
Department of Chemistry and Biochemistry, University of Windsor, Windsor, ON, N9B 3P4, Canada, Fax: (+1) 519-973-7098
Search for more papers by this authorS.J.L. is grateful to the NSERC of Canada for awarding of a Discovery Grant in support of this research.
Graphical Abstract
Anionische Räder für kationische Achsen: Elektrostatische Ion-Ion-Wechselwirkungen führen zu beträchtlich stabilen Rotaxankomplexen. In hochpolaren Lösungsmitteln wird die Bildung von [2]Pseudorotaxanen beobachtet, in denen Kronenether-Räder (siehe Bild, rot) mit anionischen Sulfonatgruppen die Pyridiniumkationen der Achse (blau) ausgleichen.
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