Porous Coordination Polymer with π Lewis Acidic Pore Surfaces, {[Cu3(CN)3{hat(CN)3(OEt)3}]⋅3 THF}n†
Daisuke Tanaka Dr.
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorShigeyuki Masaoka Dr.
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorSatoshi Horike
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorShuhei Furukawa Dr.
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorMotohiro Mizuno Prof. Dr.
Department of Chemistry, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma, Kanazawa, Ishikawa 920-1192, Japan
Search for more papers by this authorKazunaka Endo Prof. Dr.
Department of Chemistry, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma, Kanazawa, Ishikawa 920-1192, Japan
Search for more papers by this authorSusumu Kitagawa Prof. Dr.
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorDaisuke Tanaka Dr.
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorShigeyuki Masaoka Dr.
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorSatoshi Horike
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorShuhei Furukawa Dr.
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorMotohiro Mizuno Prof. Dr.
Department of Chemistry, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma, Kanazawa, Ishikawa 920-1192, Japan
Search for more papers by this authorKazunaka Endo Prof. Dr.
Department of Chemistry, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma, Kanazawa, Ishikawa 920-1192, Japan
Search for more papers by this authorSusumu Kitagawa Prof. Dr.
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
Search for more papers by this authorhat=hexaazatriphenylene. This work was supported by a Grants-in-Aid for Scientific Research in a Priority Area “Chemistry of Coordination Space” (#434) and a Grant-in-Aid for Young Scientists (B) (#17750125) from the Ministry of Education, Culture, Sports, Science and Technology, Government of Japan.
Graphical Abstract
Neutrale organische Gastmoleküle sind in den Hohlräumen eines porösen Koordinationspolymers eingeschlossen. Dabei wechselwirken hauptsächlich elektronenarme π-Ebenen der Polymeroberfläche mit elektronegativen Atomen der Gastmoleküle (siehe Bild). Der thermogravimetrischen Analyse zufolge bilden Gastmoleküle mit zwei elektronegativen Atomen stabilere Komplexe mit dem Polymer als solche mit nur einem elektronegativen Atom.
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