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Synthesis of an Optically Active C₁-Symmetric Al(salalen) Complex and Its Application to the Catalytic Hydrophosphonylation of Aldehydes^†

Bunnai Saito

Department of Chemistry, Faculty of Science, Graduate School, Kyushu University, 33, Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan, Fax: (+81) 92-642-2607

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Tsutomu Katsuki Prof.,

Tsutomu Katsuki Prof.

[email protected]

Department of Chemistry, Faculty of Science, Graduate School, Kyushu University, 33, Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan, Fax: (+81) 92-642-2607

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Bunnai Saito,

Bunnai Saito

Department of Chemistry, Faculty of Science, Graduate School, Kyushu University, 33, Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan, Fax: (+81) 92-642-2607

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Tsutomu Katsuki Prof.,

Tsutomu Katsuki Prof.

[email protected]

Department of Chemistry, Faculty of Science, Graduate School, Kyushu University, 33, Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan, Fax: (+81) 92-642-2607

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First published: 08 July 2005

https://doi.org/10.1002/ange.200501008

Citations: 37

^†

Financial support was provided by CREST of the Japan Science and Technology Agency. B.S. is grateful for research fellowships from the Japan Society for the Promotion of Science for Young Scientists. Salalen refers to an achiral hybrid salan/salen tetradentate ligand.

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Graphical Abstract

Beachtlich universell: Der chirale trigonal-bipyramidale Al(salalen)-Komplex 1 wurde synthetisiert und als Katalysator in der enantioselektiven Hydrophosphonylierung von Aldehyden mit Dimethylphosphit getestet (siehe Schema). Dies ist der erste Fall, in dem ein molekularer Katalysator sowohl aromatische als auch aliphatische Aldehyde mit Enantioselektivitäten über 80 % ee umsetzt.

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Volume117, Issue29

July 18, 2005

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Synthesis of an Optically Active C₁-Symmetric Al(salalen) Complex and Its Application to the Catalytic Hydrophosphonylation of Aldehydes^†

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Synthesis of an Optically Active C1-Symmetric Al(salalen) Complex and Its Application to the Catalytic Hydrophosphonylation of Aldehydes†

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Synthesis of an Optically Active C₁-Symmetric Al(salalen) Complex and Its Application to the Catalytic Hydrophosphonylation of Aldehydes^†