Volume 116, Issue 47 pp. 6648-6653
Zuschrift

Molecular-Mechanical Switch-Based Solid-State Electrochromic Devices

David W. Steuerman Dr.

David W. Steuerman Dr.

The California NanoSystems Institute, and Department of Chemistry and Biochemistry, University of California, Los Angeles, 405 Hilgard Avenue, Los Angeles, CA 90 095-1569, USA, Fax: (+1) 310-206-1843

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Hsian-Rong Tseng Dr.

Hsian-Rong Tseng Dr.

The California NanoSystems Institute, and Department of Chemistry and Biochemistry, University of California, Los Angeles, 405 Hilgard Avenue, Los Angeles, CA 90 095-1569, USA, Fax: (+1) 310-206-1843

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Andrea J. Peters Dr.

Andrea J. Peters Dr.

The California NanoSystems Institute, and Department of Chemistry and Biochemistry, University of California, Los Angeles, 405 Hilgard Avenue, Los Angeles, CA 90 095-1569, USA, Fax: (+1) 310-206-1843

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Amar H. Flood Dr.

Amar H. Flood Dr.

The California NanoSystems Institute, and Department of Chemistry and Biochemistry, University of California, Los Angeles, 405 Hilgard Avenue, Los Angeles, CA 90 095-1569, USA, Fax: (+1) 310-206-1843

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Jan O. Jeppesen Dr.

Jan O. Jeppesen Dr.

The California NanoSystems Institute, and Department of Chemistry and Biochemistry, University of California, Los Angeles, 405 Hilgard Avenue, Los Angeles, CA 90 095-1569, USA, Fax: (+1) 310-206-1843

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Kent A. Nielsen

Kent A. Nielsen

The California NanoSystems Institute, and Department of Chemistry and Biochemistry, University of California, Los Angeles, 405 Hilgard Avenue, Los Angeles, CA 90 095-1569, USA, Fax: (+1) 310-206-1843

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J. Fraser Stoddart Prof.

J. Fraser Stoddart Prof.

The California NanoSystems Institute, and Department of Chemistry and Biochemistry, University of California, Los Angeles, 405 Hilgard Avenue, Los Angeles, CA 90 095-1569, USA, Fax: (+1) 310-206-1843

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James R. Heath Prof.

James R. Heath Prof.

Division of Chemistry and Chemical Engineering, MC 127-72, California Institute of Technology, 1200 East California Boulevard, Pasadena, CA 91125, USA, Fax: (+1) 626-395-2355

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First published: 01 December 2004
Citations: 61

This research was funded by the Office of Naval Research, the National Science Foundation, and the Moletronics Program of the Defense Advanced Research Projects Agency, the Microelectronics Advanced Research Corporation, its Focus Centers on Functional Engineered NanoArchitectonics and Advanced Materials and Devices, and the Center for Nanoscale Innovation for Defense.

Graphical Abstract

Mit bloßem Auge lässt sich die Farbänderung erkennen, die in einer Polymermatrix auftritt, wenn das gezeigte bistabile Rotaxan zwischen den für den Grundzustand (grün) und den metastabilen Zustand (rot) stehenden Cokonformeren wechselt. Damit ist nicht nur eine elektrochrome Baueinheit in Reichweite, sondern es scheint sogar ein universeller Schaltmechanismus im Bereich des Möglichen.

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