Highly Stable Metal Hydrous Oxide Colloids by Inorganic Polycondensation in Suspension†
Corine Gérardin Dr.
Laboratoire de Matériaux Catalytiques et Catalyse en Chimie Organique, UMR 5618 CNRS ENSCM, 8, rue de L'Ecole Normale, 34296 Montpellier cedex 5, France, Fax: (+33) 4-6716-3465
Search for more papers by this authorNicolas Sanson
Laboratoire de Matériaux Catalytiques et Catalyse en Chimie Organique, UMR 5618 CNRS ENSCM, 8, rue de L'Ecole Normale, 34296 Montpellier cedex 5, France, Fax: (+33) 4-6716-3465
Search for more papers by this authorFrédéric Bouyer Dr.
Laboratoire de Matériaux Catalytiques et Catalyse en Chimie Organique, UMR 5618 CNRS ENSCM, 8, rue de L'Ecole Normale, 34296 Montpellier cedex 5, France, Fax: (+33) 4-6716-3465
Search for more papers by this authorFrançois Fajula Dr.
Laboratoire de Matériaux Catalytiques et Catalyse en Chimie Organique, UMR 5618 CNRS ENSCM, 8, rue de L'Ecole Normale, 34296 Montpellier cedex 5, France, Fax: (+33) 4-6716-3465
Search for more papers by this authorJean-Luc Putaux Dr.
Centre de Recherches sur les Macromolécules Végétales CNRS, associated with the Joseph Fourier University of Grenoble, France
Search for more papers by this authorMathieu Joanicot Dr.
CNRS Rhodia Complex Fluids Laboratory, Rhodia Inc., Cranbury, NJ 08512, USA
Search for more papers by this authorThierry Chopin Dr.
Rhodia Centre de Recherches d'Aubervilliers, 93308 Aubervilliers, France
Search for more papers by this authorCorine Gérardin Dr.
Laboratoire de Matériaux Catalytiques et Catalyse en Chimie Organique, UMR 5618 CNRS ENSCM, 8, rue de L'Ecole Normale, 34296 Montpellier cedex 5, France, Fax: (+33) 4-6716-3465
Search for more papers by this authorNicolas Sanson
Laboratoire de Matériaux Catalytiques et Catalyse en Chimie Organique, UMR 5618 CNRS ENSCM, 8, rue de L'Ecole Normale, 34296 Montpellier cedex 5, France, Fax: (+33) 4-6716-3465
Search for more papers by this authorFrédéric Bouyer Dr.
Laboratoire de Matériaux Catalytiques et Catalyse en Chimie Organique, UMR 5618 CNRS ENSCM, 8, rue de L'Ecole Normale, 34296 Montpellier cedex 5, France, Fax: (+33) 4-6716-3465
Search for more papers by this authorFrançois Fajula Dr.
Laboratoire de Matériaux Catalytiques et Catalyse en Chimie Organique, UMR 5618 CNRS ENSCM, 8, rue de L'Ecole Normale, 34296 Montpellier cedex 5, France, Fax: (+33) 4-6716-3465
Search for more papers by this authorJean-Luc Putaux Dr.
Centre de Recherches sur les Macromolécules Végétales CNRS, associated with the Joseph Fourier University of Grenoble, France
Search for more papers by this authorMathieu Joanicot Dr.
CNRS Rhodia Complex Fluids Laboratory, Rhodia Inc., Cranbury, NJ 08512, USA
Search for more papers by this authorThierry Chopin Dr.
Rhodia Centre de Recherches d'Aubervilliers, 93308 Aubervilliers, France
Search for more papers by this authorThe authors acknowledge financial support provided by Rhodia. We thank M. Destarac (Rhodia Aubervilliers, France) for providing the copolymers, L. Auvray for help in neutron scattering measurements, performed at Laboratoire Leon Brillouin, CEA Saclay, France, J.-P. Selzner (Laboratoire de Microscopie Electronique, Université Montpellier II, France) for help in TEM measurements on the Jeol 1200 EXII microscope, and M. In (Montpellier) and J. P. Jolivet (Paris) for discussions.
Graphical Abstract
Hybridische Kern-Kranz-Nanoarchitekturen (siehe Schema, Mitte) eignen sich als supramolekulare Vorstufen für beständige Metallhydroxid-Kolloide (rechts). Die hydrophilen anionisch-neutralen Blockcopolymere ermöglichen Metallhydrolyse und -kondensation in Suspension. Die Größe der Partikel und ihre Morphologie können über das Ausmaß der Metallkomplexierung eingestellt werden.
References
- 1E. Matijevic, Annu. Rev. Mater. Sci. 1985, 15, 483.
- 2E. Matijevic, Langmuir 1994, 10, 8.
- 3J. P. Jolivet, Metal Oxide Chemistry and Synthesis: From Solution to Solid State, Wiley, Chichester, 2000.
- 4W. Stumm, Colloids Surf. A 1993, 73, 1.
- 5M. Antonietti, S. Heinz, Nachr. Chem. Tech. Lab. 1992, 40, 308.
- 6M. Moffit, A. Eisenberg, Chem. Mater. 1995, 7, 1178.
- 7S. Forster, M. Antonietti, Adv. Mater. 1998, 10, 195.
10.1002/(SICI)1521-4095(199802)10:3<195::AID-ADMA195>3.0.CO;2-V CAS PubMed Web of Science® Google Scholar
- 8“Reactions and Synthesis in Surfactant Systems”: C. Göltner, Surfactant Sci. Ser. 2001, 100, 797.
- 9M. P. Pileni, Langmuir 1997, 13, 3266.
- 10“Reactions and Synthesis in Surfactant Systems”: L. Jeunieau, F. Debuigne, J. B. Nagy, Surfactant Sci. Ser. 2001, 100.
- 11H. Sakai, H. Kawahara, M. Shimazaki, M. Abe, Langmuir 1998, 14, 2208.
- 12H. Cölfen, Macromol. Rapid Commun. 2001, 22, 219–252.
- 13J. M. Marentette, J. Norwig, E. Stockelmann, W. H. Meyer, G. Wegner, Adv. Mater. 1997, 9, 647.
- 14H. Cölfen, M. Antonietti, Langmuir 1998, 14, 582.
- 15L. Qi, H. Cölfen, M. Antonietti, Chem. Mater. 2000, 12, 2392.
- 16A. Taubert, D. Palms, O. Weiss, M.-T. Piccini, D. N. Batchelder, Chem. Mater. 2002, 14, 2594.
- 17S. N. Sidorov, L. M. Bronstein, P. M. Valetsky, J. Hartmann, H. Cölfen, H. Schnablegger, M. Antonietti, J. Colloid Interface Sci. 1999, 212, 107–211.
- 18Y. Matsai, M. Sedlak, H. Colfen, M. Antonietti, Chem. Eur. J. 2002, 8, 2429.
- 19L. Allouche, C. Gérardin, T. Loiseau, G. Férey, F. Taulelle, Angew. Chem. 2000, 112, 521–524;
10.1002/(SICI)1521-3757(20000204)112:3<521::AID-ANGE521>3.0.CO;2-6 Google ScholarAngew. Chem. Int. Ed. 2000, 39, 511–514.10.1002/(SICI)1521-3773(20000204)39:3<511::AID-ANIE511>3.0.CO;2-N CAS PubMed Web of Science® Google Scholar
- 20J. S. Pedersen, M. C. Gerstenberg, Macromolecules 1996, 29, 1363.
- 21J. S. Pedersen, C. Svaneborg, Curr. Opin. Colloid Interface Sci. 2002, 7, 158.
- 22I. W. Hamley, J. S. Pedersen, C. Booth, V. M. Nace, Langmuir 2001, 17, 6386.
- 23P. Hervé, M. Destarac, J.-F. Berret, J. Lal, J. Oberdisse, I. Grillo, Europhys. Lett. 2002, 58, 912.
- 24C.-I. Huang, M. Olvera de la Cruz, Macromolecules 2002, 35, 976–986.
- 25A. V. Kabanov, T. K. Bronich, V. A. Kabanov, K. Yu, A. Eisenberg, Macromolecules 1996, 29, 6797.
- 26A. Harada, K. Kataoka, Science 1999, 283, 65.
- 27A. Harada, K. Kataoka, Macromol. Symp. 2001, 172, 1–9.
- 28L. M. Bronstein, S. N. Sidorov, P. Valetsky, J. Hartmann, H. Colfen, M. Antonietti, Langmuir 1999, 15, 6256.
- 29Y. Li, Y-K. Gong, K. Nakashima, Y. Murata, Langmuir 2002, 18, 6727.
- 30D. Taton, A.-Z. Wilczewska, M. Destarac, Macromol. Rapid Commun. 2001, 22, 1497–1503.
- 31J. L. Putaux, A. Buléon, R. Borsali, H. Chanzy, Int. J. Biol. Macromol. 1999, 26, 145.
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