Nachdem die Strukturen von AuH und AuI bereits bekannt waren, konnten in der Hydridreihe jetzt die lang gesuchten Goldhydride AuH₃ (=(H₂)AuH) und AuH₅ (=(H₂)AuH₃) mithilfe von Matrixisolations-Techniken erstmals experimentell identifiziert werden. Als globales Minimum von AuI₃, einem fehlenden Glied in der Gruppe der Goldhalogenide, scheint das L-Isomer (C_s-Symmetrie; Charge-Transfer von I₂ auf AuI) aufhand neuerer Rechnungen am wahrscheinlichsten.

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Volume114, Issue13

July 3, 2002

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