Alumoxane Hydride and Aluminum Chalcogenide Hydride Compounds with Pyrazolato Ligands
Wenjun Zheng Dipl.-Chem.
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorNadia C. Mösch-Zanetti Dr.
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorHerbert W. Roesky Prof. Dr.
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorMathias Noltemeyer Dr.
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorManuel Hewitt
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorHans-Georg Schmidt
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorThomas R. Schneider Dr.
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorWenjun Zheng Dipl.-Chem.
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorNadia C. Mösch-Zanetti Dr.
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorHerbert W. Roesky Prof. Dr.
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorMathias Noltemeyer Dr.
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorManuel Hewitt
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorHans-Georg Schmidt
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorThomas R. Schneider Dr.
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorThis work was supported by the Deutsche Forschungsgemeinschaft. N.C.M.-Z. thanks the Schweizerischer Nationalfonds for a fellowship and W.Z. thanks Dr. U. Ritter for the GC analysis.
Abstract
Zwei fünffach koordinierte Aluminiumatome enthält der planare Al2O2-Kern in 1, der zudem ungewöhnlich kurze Al-O-Bindungen aufweist. 1 wurde aus einem Aluminiumdihydrid-Komplex und Dioxan synthetisiert. Aus dem Edukt können durch Reaktionen mit S, Se und Te weitere chalkogenverbrückte Aluminiumhydride entstehen.
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