Synthesis and Structure of a Monomeric Aluminum(I) Compound [{HC(CMeNAr)2}Al] (Ar=2,6–iPr2C6H3): A Stable Aluminum Analogue of a Carbene
Chunming Cui Dipl.-Chem.
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorHerbert W. Roesky Prof. Dr.
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorHans-Georg Schmidt
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorMathias Noltemeyer Dr.
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorHaijun Hao
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorFanica Cimpoesu
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorChunming Cui Dipl.-Chem.
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorHerbert W. Roesky Prof. Dr.
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorHans-Georg Schmidt
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorMathias Noltemeyer Dr.
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorHaijun Hao
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorFanica Cimpoesu
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany) Fax: (+49) 551-393373
Search for more papers by this authorThis work was supported by the Deutsche Forschungsgemeinschaft.
Abstract
Ein „Aluminiumcarben“: [{HC(CMeNAr)2}Al] zeigt ein planares heterocyclisches Al-N-C-C-C-N-Sechsringsystem mit einem zweifach koordinierten Aluminiumatom mit freiem Elektronenpaar (siehe Bild), wodurch die Verbindung den Charakter einer Lewis-Base erhält. Hergestellt wird das Monomer durch Reduktion des entsprechenden Aluminium(III)-diiodids.
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