Margarines and Spreads
Michael M. Chrysan
USDA-ARS National Center for Agricultural Utilization Research, ARS, Peoria, IL, USA
Search for more papers by this authorHong-Sik Hwang
USDA-ARS National Center for Agricultural Utilization Research, ARS, Peoria, IL, USA
Search for more papers by this authorMichael M. Chrysan
USDA-ARS National Center for Agricultural Utilization Research, ARS, Peoria, IL, USA
Search for more papers by this authorHong-Sik Hwang
USDA-ARS National Center for Agricultural Utilization Research, ARS, Peoria, IL, USA
Search for more papers by this authorAbstract
This article discusses margarines and spreads, which were developed as butter substitutes. Trends of historical production, consumption, and constituents, as well as regulatory status in the United States including standards of identity and labeling, label claims, and regulations for trans-fats are discussed. Product characteristics such as spreadability, oil separation, and melting and ingredients including oils, oil blends, milk products, proteins, emulsifiers, preservatives, and coloring agents are also covered. In addition, processing and other specialty spreads are discussed in this article.
References
- 1Walsh, B. (2014). Time Mag. 30–35. June 23.
- 2Legrand, P. (2016). Pratiques en Nutr. 12: 23–26.
10.1016/j.pranut.2016.06.007 Google Scholar
- 3Sandoiu, A. (2018). Medical News Today https://www.medicalnewstoday.com/articles/322452.php (accessed 20 December 2018).
- 4Pimpin, L., Wu, J.H.Y., Haskelberg, H. et al. (2016). Plos One 11: 1–18.
10.1371/journal.pone.0158118 Google Scholar
- 5 S.F. Riepma (ed.) (1970). The Story of Margarine. Washington, DC: Public Affairs Press.
- 6Miksta, S.C. (1971). J. Am. Oil Chem. Soc. 48: 169A–172A.
10.1007/BF02544926 Google Scholar
- 7Snodgrass, K. (1930). Margarine as a Butter Substitute, 121–123. Food Research Institute, Stanford University.
- 8 W. Clayton (ed.) (1920). Margarine. London/New York: Longmans Green.
- 9 U.S. Food and Drug Administration (2018). Code Fed. Reg., Title 21.
- 10 U.S. Food and Drug Administration (1976). Fed. Reg. 41: 36509.
- 11 U.S. Food and Drug Administration (1993). Fed. Reg. 58: 2066.
- 12 U.S. Food and Drug Administration (1993). Fed. Reg. 58: 17096, 17171, 17328.
- 13 U.S. Food and Drug Administration (1993). Fed. Reg. 58: 44020.
- 14 U.S. Food and Drug Administration (2003). Fed. Reg. 133: 41434.
- 15Erickson, B.E. (2015). Chem. Eng. News 93: 6.
- 16De Man, J.M., Dobbs, J.E., and Sherman, P. (1979). In: Food Texture and Rheology (ed. P. Sherman), 43–54. New York: Academic Press.
- 17 American Oil Chemists' Society (2017). Official Methods and Recommended Practices, 7e. Champaign, IL: AOCS Press, Method Cc 16–60, Reapproved.
- 18De Man, J.M. and Beers, A.M. (1987). J. Texture Stud. 18: 303–318.
10.1111/j.1745-4603.1987.tb00908.x Google Scholar
- 19De Man, J.M. (1983). J. Am. Oil Chem. Soc. 60: 82–87.
- 20Haighton, A.J. (1959). J. Am. Oil Chem. Soc. 36: 345–348.
- 21Rohm, H. and Raaber, S. (1991). J. Sensory Stud. 8: 81–88.
10.1111/j.1745-459X.1991.tb00504.x Google Scholar
- 22Kamel, B.S. and De Man, J.M. (1975). Can. Inst. Food Sci. Technol. J. 8: 117–121.
- 23Board, P.W., Aichen, K., and Kuskis, A. (1980). J. Food Technol. 15: 277–283.
- 24Tanaka, M., De Man, J.M., and Voisey, P.W. (1971). J. Texture Stud. 2: 306–315.
- 25Prentice, J.H. (1954). Lab. Pract. 3: 186–189.
- 26Vasic, I. and De Man, J.M. (1967). J. Am. Oil Chem. Soc. 44: 225–228.
- 27Shama, F. and Sherman, P. (1970). J. Texture Stud. 1: 196–205.
- 28Stern, P. and Cmolik, J. (1976). J. Am. Oil Chem. Soc. 53: 644–647.
- 29Kokini, J.L. and Dickie, A. (1982). J. Texture Stud. 13: 211–227.
- 30Haighton, A.J. (1969). J. Am. Oil Chem. Soc. 46: 570.
- 31De Man, L., De Man, J.M., and Blackman, B. (1989). J. Am. Oil Chem. Soc. 66: 128–132.
- 32De Man, L., Postmus, E., and De Man, J.M. (1990). J. Am. Oil Chem. Soc. 67: 323–328.
- 33De Man, L., Chen, C.F., and De Man, J.M. (1991). J. Am. Oil Chem. Soc. 68: 70–73.
- 34Seiden, P. (1965). Margarine oils. Canadian Patent 718,372 (21 September 1965), (to Procter and Gamble Ltd.).
- 35De Man, J.M. and Wood, F.W. (1958). J. Dairy Sci. 41: 369–374.
- 36Lomneth, R.B. and Blair, D.R. (1983). Margarine and method for making same. U.S. Patent 4,388,339A (14 June 1983), (to Procter and Gamble Ltd.).
- 37Borwankar, R.P., Frye, L.A., Blaurock, A.E., and Sasevich, F.J. (1992). J. Food Eng. 16: 55–74.
- 38Lutton, E.S. (1958). 5th Margarine Research Symposium, October 17, 1958.
- 39Balinov, B., Söderman, O., and Wärnheim, T. (1994). J. Am. Oil Chem. Soc. 71: 513–518.
- 40Callaghan, P.T., Jolley, K.W., and Humphrey, R.S. (1983). J. Coll. Interface Sci. 93: 521–529.
- 41Packer, K.J. and Rees, C. (1972). J. Coll. Interface Sci. 40: 206–218.
- 42Zschaler, R. (1977). Fette Seifen Anstrichm. 79: 107–109.
- 43Poot, C., Verburg, C.C., Kirton, D.C., et al. (1978). Fractionated co-randomized fat blend and use. U.S. Patent 4,087,564 (2 May 1978), (to Lever Brothers).
- 44Moran, D.P.J. (1978). Phase inverting low fat spreads. U.S. Patent 4,115,598 (19 September 1978), (to Lever Brothers).
- 45Galindo-Cuspinera, V., Sousa J.V., and Knoop, M., (2017). J. Texture. Stud. 48: 302–312.
- 46Postmus, E., De Man, L., and De Man, J.M. (1989). Can. Inst. Food Sci. Technol. J. 22: 481–486.
- 47Garsetti, M., Balentine, D.A., Zock, P.L. et al. (2016). Int. J. Food Sci. Nutr. 67: 372–382.
- 48 U.S. Food and Drug Administration (1985). Fed. Reg. 50: 3745.
- 49Yamoneka, J., Malumba, P., Lognay, G. et al. (2019). LWT 101: 747–756.
- 50Stansby, M.E. (1973). J. Am. Oil Chem. Soc. 50: 220A–225A.
- 51Heertje, I. (1993). Food Struct. 12: 77–94.
- 52Juriaanse, A.C. and Heertje, I. (1988). Food Microstruct. 7: 181–188.
- 53Haighton, A.J. (1976). J. Am. Oil Chem. Soc. 53: 397–399.
- 54Lefebvre, J. (1983). J. Am. Oil Chem. Soc. 60: 295–299.
- 55 American Oil Chemists' Society (1989). Official Methods and Recommended Practices of the AOCS, 6e. Champaign, IL: AOCS Press, AOCS Official Method Cd 10–57, Reapproved.
- 56 American Oil Chemists' Society (2017). Official Methods and Recommended Practices of the AOCS, 7e. Champaign, IL: AOCS Press, AOCS Official Method Cd 16-81, Reapproved.
- 57Enden, J.C., Haighton, A.J., Putte, K. et al. (1978). Fette Seifen Anstrichm. 80: 180–186.
- 58Lutton, E.S. (1972). J. Am. Oil Chem. Soc. 49: 1–9.
- 59Hoerr, C.W. (1964). J. Am. Oil Chem. Soc. 41: A4–A34.
- 60Wilton, I. and Wode, G. (1963). J. Am. Oil Chem. Soc. 40: 707–711.
- 61Simpson, T.D. and Hagemann, J.W. (1982). J. Am. Oil Chem. Soc. 59: 169–171.
- 62Hernqvist, L. and Larsson, K. (1982). Fette Seifen Anstrichm. 84: 349–354.
- 63Kellens, M. and Reynaers, H. (1992). Fett Wiss. Technol. 94: 286, 294.
- 64Riiner, U. (1971). Lebensm. Wiss. Technol. 4: 175–179.
- 65Vaisey-Genser, M., Vane, B.K., and Johnson, S. (1989). J. Texture Stud. 20: 347–361.
- 66Wiedermann, L.H. (1978). J. Am. Oil Chem. Soc. 55: 823–829.
- 67Zeitoun, M.A.M., Neff, W.E., List, G.R., and Mounts, T.L. (1993). J. Am. Oil Chem. Soc. 70: 467–471.
- 68Aronhime, J.S., Sarig, S., and Garti, N. (1988). J. Am. Oil Chem. Soc. 65: 1144–1150.
- 69Weinberg, B. (1972). Can. Inst. Food Sci. Technol. J. 5: A57–A60.
- 70Persmark, V. and Bengtsson, L. (1976). Riv. Ital. Sostanze Grasse 3: 307–311.
- 71Hernqvist, L. and Anjou, K. (1983). Fette Seifen Anstrichm. 85: 64–66.
- 72Hernqvist, L., Herslof, B., Larsson, K., and Podlaha, O. (1981). J. Sci. Food Agric. 32: 1197–1202.
- 73Wahnelt, V.S., Meusel, D., and Tülsner, M. (1991). Fat Sci. Technol. 93: 117–121.
- 74Gander, K.F. and Gander, K.F. (1969). Margarine etc. Canadian Patent 830,938 (30 December 1969), (to Unilever).
- 75Freier, B., Popescu, O., Ille, A.M., and Antoni, H. (1973). Ind. Aliment. 24: 604–607.
- 76Krog, N. (1977). J. Am. Oil Chem. Soc. 54: 124–131.
- 77Lee, S. and de Man, J.M. (1984). Fette Seifen Anstrichm. 86: 460–465.
- 78Hojerová, J., Schmidt, S., and Krempasky, J. (1992). Food Struct. 11: 147–154.
- 79Sato, K. and Kuroda, T. (1987). J. Am. Oil Chem. Soc. 64: 124–127.
- 80Shen, C.F., De Man, L., and De Man, J.M. (1990). Elaeis 2: 143–156.
- 81Cho, F. and De Man, J.M. (1993). J. Food Lipids 1: 53–68.
- 82Ward, J. (1988). J. Am. Oil Chem. Soc. 65: 1731–1733.
- 83Belyaeva, G.K., Kozin, N.I., Golosava, V.S., and Fal'k, E. (1969). Maslozhirovaya Promyshlennost 38: 15–16.
- 84Madsen, J. (1973). Zesz. Probl. Postepow Nauk Roln. (136): 147.
- 85van der Hoek, W. (1969). Rev. Fr. Corps Gras 16: 761.
- 86D'Souza, V., De Man, L., and De Man, J.M. (1991). J. Am. Oil Chem. Soc. 68: 153–162.
- 87D'Souza, V., De Man, L., and De Man, J.M. (1992). J. Am. Oil Chem. Soc. 69: 1198–1205.
- 88Blanc, I. (1969). Rev. Fr. Corps Gras 16: 457–471.
- 89Riiner, U. (1970). Lebensm. Wiss. Technol. 3: 101–106.
- 90Riiner, U. (1971). Lebensm. Wiss. Technol. 4: 76–80.
- 91Berger, K.G. (1975). Chem. Ind. 910–913.
- 92Jacobsberg, B. and Ho, O.C. (1976). J. Am. Oil Chem. Soc. 53: 609–617.
- 93Okiy, D.A. (1978). Oleagineaux 33: 625–628.
- 94Yap, P.H., De Man, J.M., and De Man, L. (1989). Fat Sci. Technol. 91: 178–180.
- 95Sambuc, E., Dirik, Z., Reymond, G., and Naudet, M. (1980). Rev. Fr. Corps Gras 27: 505–512.
- 96Sambuc, E., Dirik, Z., Reymond, G., and Naudet, M. (1981). Rev. Fr. Corps Gras 28: 13–19.
- 97Chikany, B. (1982). Olaj Szappan Kosmet. 31: 107; through Food Sci. Technol. Abstr., No. 10. N0472 (1983).
- 98Kattenberg, H.R. and Poot, C. (1977). Margarine fat blend. U.S. Patent 4,016,302 (5 April 1977), (to Lever Brothers).
- 99Yuki, A., Matsuda, K., and Nishimura, A. (1990). J. Jpn. Oil Chem. Soc. 39: 236–244.
- 100Van Meeteren, J.A. and Wesdorp, L.H. (1995). Improvements in edible fats. European Patent 0,498,487B1 (26 April 1995), (to Unilever).
- 101Young, F.V.K. (1983). J. Am. Oil Chem. Soc. 60: 374–379.
- 102Ribeiro, A.P.B., Gonçalves, L.A.G., Gioielli, L.A., and Basso, R.C. (2013). In: Advance in Food Science and Technology (ed. P.M. Visakh, S. Thomas, L.B. Iturriaga and P.D. Ribotta), 113–182. Beverly, MA: Scrivener Publishing LLC.
- 103Cho, F., De Man, J.M., and Allen, O.B. (1993). J. Food Lipids 1: 25–52.
- 104Wieske, T. (1977). 7th European Symposium, European Federation of Chemical Engineering Food Working Party. 214–224.
- 105Wieske, T. (1977). Fat compositions. British Patent Application 1,479,287A (13 July 1977), (to Unilever).
- 106Pelloso, T.A. and Kogan, L. (1982). Sunflower-oil-based edible fat product. U.S. Patent 4,316,919A (23 February 1982), (to Nabisco Brands Inc.).
- 107Heider, H. and Wieske, T. (1980). Margarine fat. U.S. Patent 4,230,737 (28 October 1980), (to Lever Brothers Co.).
- 108McNaught, J.P. (1975). Randomly interesterified sunflower and tobaccoseed oils. U.S. Patent 3,900,503 (19 August 1975), (to Lever Brothers Co.).
- 109Mensink, R.P. and Katan, M.B. (1990). N. Engl. J. Med. 323: 439–445.
- 110Zock, P.L. and Katan, M.B. (1992). J. Lipid Res. 33: 399–410.
- 111Mensink, R.P., Zock, P.L., Katan, M.B., and Hornstra, G. (1992). J. Lipid Res. 33: 1493–1501.
- 112Lichtenstein, A.H., Ausman, L.M., Carrasco, W. et al. (1993). Arterioscler. Thromb. Vasc. Biol. 13: 154–161.
- 113Wood, R., Kubena, K., O'Brien, B. et al. (1993). J. Lipid Res. 34: 1–11.
- 114Siguel, E.N. and Lerman, R.H. (1993). Am. J. Cardiol. 71: 916–920.
- 115Troisi, R., Willett, W.C., and Weiss, S.T. (1992). Am. J. Clin. Nutr. 56: 1019–1024.
- 116Willett, W.C., Stampfer, M.J., Manson, J.E. et al. (1993). Lancet 341: 581–585.
- 117Judd, J.T., Clevidence, B.A., Muesing, R.A. et al. (1994). Am. J. Clin. Nutr. 59: 861–868.
- 118Anonymous (1994). Food Labeling News 2 (21): 15.
- 119Haumann, B.F. (1994). Inform 5: 346, 350, 352, 354, 356, 358.
- 120Sabasranamam, M.S. (2004). Trans free hard structural fat for margarine blend and spreads. U.S. Patent 6,808,737B2 (26 October 2004), (to Premium Vegetable Oils Berhad).
- 121Ward, J. (1982). Trans free hard structural fat for margarine blend and spreads. U.S. Patent 4,341,812 (27 July 1982), (to Nabisco Brands Inc.)
- 122Ward, J. (1982). Edible fat product II. U.S. Patent 4,341,813 (27 July 1982), (to Nabisco Brands Inc.).
- 123Graffelman, H.A. (1971). Margarine fat and process for preparing a spread. U.S. Patent 3,617,308 (2 November 1971), (to Lever Brothers Co.).
- 124Heteren, J., Pronk, J.N., Smeenk, W.J. et al. (1983). Fat blend. U.S. Patent 4,386,111 (31 May 1983), (to Lever Brothers Co.).
- 125Fondu, M. and Willems, M.G.A. (1972). Margarine fat containing randomized fat component. U.S. Patent 3,634,100 (11 January 1972), (to Lever Brothers Co.).
- 126Keuning, R., Haighton, A.J. and Dijkshoorn, W. (1982). Process for the dry fractionation of oils and fats having a steep dilatation/temperature line and use of the fractionated fats in margarines and shortenings. U.S. Patent 4,360,536 (23 November 1982), (to Lever Brothers Co.).
- 127Dijkshoorn, W., Huizinga, H., and Pronk, J.N. (1982). Fat blend substantially free of hydrogenated and interesterified fats. U.S. Patent 4,366,181 (28 December 1982), (to Lever Brothers Co.).
- 128Nagoh, A., Ebihara, Y., and Miyabe, M. (1995). Process for producing hard stocks. European Patent 0,526,980B1 (6 December 1995), (to Fuji Oil Co. Ltd.).
- 129List, G.R., Emken, E.A., Kwolek, W.F. et al. (1977). J. Am. Oil Chem. Soc. 54: 408–413.
- 130Zeitoun, M.A.M., Neff, W.E., and Mounts, T.L. (1992). Rev. Fr. Corps Gras 39: 85–90.
- 131Eiilott, W., Greep, M.R.J., Van Meeteren, J.A. et al. (1996). Edible spread. European Patent 0,369,519B1 (22 May 1996), (to Unilever).
- 132Feeney, R.D., Gross, A., and Zaks, A. (1992). Fat soluble polymers and their use in foods. International Patent Application WO1992003937A3 (30 April 1992), (to Opta Food Ingredients, Inc.).
- 133Stahl, M. (1981). Easily digested margarine and low calorie spread - contg. fatty acid monoglyceride with medium chain tri:glyceride and emulsifier. German Federal Republic Patent Application 2,935,572A1 (13 March 1981), (to Lepharm Pharmazeutische Entwic and GmbH).
- 134Menz, H., Rost, J.E., and Wieske, T. (1972). Spreadable fats. U.S. Patent 3,658,555 (25 April 1972), (to Lever Brothers Co.).
- 135Weiske, T. and Menz, H. (1972). Fette Seifen Anstrichm 74: 133–136.
10.1002/lipi.19720740301 Google Scholar
- 136Von Rappard, G. and Kretschmer, W. (1986). Fat compsn. contg. medium chain triglyceride mixt. - and hard fat, useful as basis for margarine. German Federal Republic Patent 2,832,636C2 (16 January 1986), (to GmbH).
- 137Roberts, B.A. (1984). Oleaginous compositions. U.S. Patent 4,446,165 (1 May 1984), (to Procter and Gamble).
- 138Orphanos, P.D., Bernhartdt, C., Madison, B.L. et al. (1990). Sucrose fatty acid ester compositions and shortenings and margarines made therefrom. U.S. Patent 4,940,601 (10 July 1990), (to Procter and Gamble).
- 139Jandacek, R.J. and Letton, J.C. (1991). Improved margarine compositions/containing solid sucrose polyester. U.S. Patent 5,017,398 (21 May 1991), (to Procter and Gamble).
- 140Cain, F.W., De Jong, F.R., Lanting-Marijs, J.A. et al. (1992). Improvements relating to spreads. European Patent Application 0,415,468A3 (5 August 1992), (to Unilever).
- 141Glueck, C.J., Hastings, M.M., Allen, C. et al. (1982). Am. J. Clin. Nutr. 35: 1352–1359.
- 142Nicolosi, R. (1990). Inform 1: 831–832.
- 143Simopoulos, A.P. (1991). Am. J. Clin. Nutr. 54: 438–463.
- 144Horrobin, D.F. (1992). Prog. Lipid Res. 31: 163–194.
- 145Young, F.V.K. (1990). Inform 1: 731–741.
- 146Bimbo, A.P. (1989). J. Am. Oil Chem. Soc. 66: 1717–1726.
- 147Young, F.V.K. (1986). The Chemical and Physical Properties of Crude Fish Oil for Refiners and Hydrogenators. Hertfordshire, UK: International Association of Fish Meal Manufacturers Issue 18 of Fish Oil Bulletin.
- 148Gunstone, F.D. (1992). Prog. Lipid Res. 31: 145–161.
- 149Renault, A. (2015). OCL–Oilseeds and fats 22 (D609): 1–11.
- 150 A.G. Marangoni and N. Garti (ed.) (2018). Edible Oleogels: Structure and Health Implications, 2e. Champaign, IL: AOCS Press.
- 151Hughes, N., Rush, J.W., and Marangoni, A.G. (2018). In: Edible Oleogels: Structure and Health Implications, 2e (ed. A.G. Marangoni and N. Garti), 381–397. Champaign, IL: AOCS Press.
10.1016/B978-0-12-814270-7.00016-2 Google Scholar
- 152O'Sullivan, C., Davidovich-Pinhas, M., Wright, A.J. et al. (2017). Food Funct. 8: 1438–1451.
- 153Tan, S.-Y., Peh, E.W.-Y., Marangoni, A.G., and Henry, C.J. (2017). Food Funct. 8: 241–249.
- 154Hwang, H.S., Singh, M., Bakota, E.L. et al. (2013). J. Am. Oil Chem. Soc. 90: 1705–1712.
- 155Hwang, H.S., Singh, M., Winkler-Moser, J.K. et al. (2014). J. Food Sci. 79: C1926–C1932.
- 156Hwang, H.S., Singh, M., and Lee, S. (2016). J. Food Sci. 81: C1045–C1054.
- 157Kim, J.Y., Lim, J., Lee, J. et al. (2017). J. Food Sci. 82: 445–452.
- 158Patel, A.R., Rajarethinem, P.S., Gredowska, A. et al. (2014). Food Funct. 5: 645–652.
- 159Stortz, T.A., Laredo, T., and Marangoni, A.G. (2015). Food Biophys. 10: 253–263.
- 160Zetzl, A.K., Marangoni, A.G., and Barbut, S. (2012). Food Funct. 3: 327–337.
- 161Botega, D.C.Z., Marangoni, A.G., Smith, A.K., and Goff, H.D. (2013). J. Food Sci. 78: C1334–C1339.
- 162Patel, S. (1980). Quality considerations in margarine oil manufacturing. ISF AOCS World Congress New York.
- 163 American Oil Chemists' Society (2017). Official Methods and Recommended Practices of the AOCS, 7e. Champaign, IL: AOCS Press, AOCS Official Method Cg 2-83, Reapproved.
- 164Wiedermann, L.H. (1972). J. Am. Oil Chem. Soc. 49: 478–480.
- 165 U.S. Food and Drug Administration (1973). Fed. Reg. 38: 25671.
- 166Smouse, T.H., Maines, M.J.K., and Allen, R.R. (1977). Margarine-like product having controlled browning properties. U.S. Patent 4,038,436 (26 July 1977), (to Anderson Clayton and Co.).
- 167Eriksson, C.E. (1982). Food Chem. 9: 3–19.
- 168Linteris, L.L. (1973). Milk-free margarine. U.S. Patent 3,721,570 (20 March 1973) (to Lever Brothers Co.).
- 169Cain, F.W., Day, J.I., Jones, M.G. et al. (1999). Edible plastified dispersion. European Patent 0,279,499B2 (24 November 1999), (to Unilever).
- 170Dziezak, J.D. (1988). Food Technol. 42: 174–180.
- 171Madsen, J. (1987). Fett Wiss. Technol. 89: 165–172.
- 172Gaonkar, A.G. and Borwankar, R.P. (1991). Colloids Surf. 59: 331–343.
- 173Schneider, M. (1992). Fett Wiss. Technol. 94: 524–533.
- 174van Nieuwenhuyzen, W. (1981). J. Am. Oil Chem. Soc. 58: 886–888.
- 175Lincklaen, H. and Rek, J. (1974). Pourable emulsion. U.S. Patent 3,796,815 (12 March 1974), (to Lever Brothers Co.).
- 176Wieske, T., Todt, K.H., De Fexter, J.A. et al. (1992). Emulsifying compositions containing a mixture of hydrolyzed and unhydrolyzed fractions and process for making same. U.S. Patent 5,079,028 (7 January 1992), (to Conopco Inc.).
- 177Duin, H.J., Van Dam, A.F., and Rek, J.H.M. (1979). Margarine. U.S. Patent 4,148,930 (10 April 1979), (to Lever Brothers Co.).
- 178Rek, J.H.M. and Jolemans, P.M.J. (1982). Process for producing a margarine having a reduced tendency to spattering . U.S. Patent 4,325,980 (20 April 1982), (to Lever Brothers Co.).
- 179Madsen, J. (1984). Res. Discl. (238): 91.
- 180Harris B.R. (1933). Emulsion. U.S. Patent 1,917,255 (11 July 1933), (to B.R. Harris).
- 181Stewart, M.F. and Hughes, E.J. (1972). Process Biochem. 7: 27–28.
- 182Gorman, W.A., Christie, R.G., and Howard, K.G. (1960). Process for manufacturing whipped fatty emulsion. U.S. Patent 2,937,093 (17 May 1960), (to National Dairy Products Corp.).
- 183Castenmiller, W.A.M., Chesters, A.K., and Ernsting, P.B. (1989). Edible plastic product. U.S. Patent 4,874,626 (17 October 1989), (to Lever Brothers Co).
- 184Brammer, K. and Wieske, T. (1975). Emulsifier system. U.S. Patent 3,889,005 (10 June 1975), (to Lever Brothers Co).
- 185Groeneweg, F., Voorst Vader, F., and Agterof, W.G.M. (1993). Chem. Eng. Sci. 48: 229–238.
- 186Heteren, J., Kelly, T.R., Livingston, R.M. et al. (1992). Spread. European Patent Application 0,420,314A3 (4 March 1992), (to Unilever).
- 187Garti, N., Binyamin, H., and Aserin, A. (1998). J. Am. Oil Chem. Soc. 75: 1825–1831.
- 188Norton, J.E. and Fryer, P.J. (2012). J. Food Eng. 113: 329–336.
- 189Matsuda, K. and Kitao, M. (1995). Water-in-oil emulsion. European Patent 0,430,180B1 (31 May 1995), (to Mitsubishi Chemical Corp.).
- 190Terada, K., Fujita, S., and Yoshida, N. (1975). Edible water in oil emulsion and method for preparing the same. U.S. Patent 3,914,458 (21 October 1975), (to Adeka Corp.).
- 191Pedersen, P.F. (1991). Res. Discl. (321): 64.
- 192Barmentlo, B. and Slater N.K. (1992). Method of preparing an emulsion spread using a wet gelatine retentate. U.S. Patent 5,145,704 (8 September 1992), (to Van den Bergh Foods Co).
- 193Kanematsu, H., Morise, E., Niiya, I. et al. (1972). J. Jpn. Soc. Food Nutr. 25: 343–348.
- 194Sherwin, E.R. (1976). J. Am. Oil Chem. Soc. 53: 430–436.
- 195Cillard, J., Cillard, P., and Cormier, M. (1980). J. Am. Oil Chem. Soc. 57: 255–261.
- 196Klaui, K. (1976). Flavours 7: 165.
- 197Muys, G.T., Verrips, C.T., and Van Gorp, R.T.S. (1976). Yeast containing food emulsions. U.S. Patent 3,995,066 (30 November 1976), (to Lever Brothers Co.).
- 198Verrips, C.T. and Vonkeman, H. (1975). Preparing margarine containing viable bacterial cells having alcohol-dehydrogenase activity. U.S. Patent 3,904,767 (9 September 1975), (to Lever Brothers Co.).
- 199Mertens, W.G., Swindells, C.E., and Teasdale, B.F. (1971). J. Am. Oil Chem. Soc. 48: 544–546.
- 200Melnick, D. (1966). High fat food products and methods of preparing same. U.S. Patent 3,243,302 (29 March 1966), (to Unilever Bestfoods North America).
- 201Verrips, C.T. and Zaalberg, J. (1980). Eur. J. Appl. Microbiol. Biotechnol. 10: 187–196.
- 202Muys, G.T. (1969). Process Biochem. 4: 31–37.
- 203 E. Luck and M. Jager (ed.) (1997). Antimicrobial Food Additives Berlin/Heidelberg/New York. Springer-Verlag.
10.1007/978-3-642-59202-7 Google Scholar
- 204Kapp, F. and Mittag, B. (1982). Lebensmittelindustrie 29: 160–162.
- 205Harris, N.E. and Rosenfield, D. (1974). Food Process. Ind. 43: 23–26.
- 206Castenon, M. and Inigo, B. (1973). Lebensmittel Wiss. Technol. 6: 70.
- 207Bodor, J., Schoenmakers, A.W., and Verhue, W.M. (1991). Spreads having a good microbiological stability and a fresh dairy taste. U.S. Patent 5,013,573 (7 May 1991), (to Van Den Bergh Foods Co.).
- 208 Anonymous (1990). Emulsion having an improved microbiological stability. Australian Patent Application 199052102 (22 March 1990), (to Unilever).
- 209Klapwijk, P.M. (1992). Food Control 3: 183–189.
10.1016/0956-7135(92)90129-X Google Scholar
- 210Siek, T.J. and Lindsay, R.C. (1970). J. Dairy Sci. 53: 700–703.
- 211Keppler, J.G. (1970). J. Agric. Food Chem. 18: 988–991.
- 212Haring, P.G.M., Van Pelt, J.G., and Andreae, C.F. (1995). Naturally flavoured food product. European Patent 0,478,036 B2 (2 November 1995), (to Unilever).
- 213Slover, H.T., Thompson, R.H., Davis, C.S., and Merola, G.V. (1985). J. Am. Oil Chem. Soc. 62: 775–786.
- 214Klaui, H. and Raunhardt, O. (1976). Alimenta 15: 37–45.
- 215 A.J.C. Andersen and P.N. Williams (ed.) (1965). Margarine, 2e. New York: Pergamon Press.
- 216Todd, P.H. (1964). Vegetable base food coloring for oleomargarine and the like. U.S. Patent 3,162,538 (22 December 1964), (to Kalamazoo Spice Extraction Co.).
- 217Sambuc, E. and Naudet, M. (1965). Rev. Fr. Corps Gras 12: 239.
- 218Presse, R., Quendt, H., and Raeuber, H. (1975). Lebensmittelindustrie 22: 34.
- 219Havenstein, A.G. and Hiffziger, A. (1994). Process for manufacture of edible spreads and apparatus for the performance of said process. European Patent 0,422,712B1 (9 March 1994).
- 220Okonogi, S., Kato, R., Asano, Y. et al. (1994). Methods for producing emulsions, low-fat spread and oil-in-water-in-oil type spread. U.S. Patent 5,279,847 (18 January 1994), (to Morinaga Milk Industry Co. Ltd.).
- 221Joyner, N.T. (1953). J. Am. Oil Chem. Soc. 30: 526–535.
- 222Heertje, I., Eendenburg, J., Cornelissen, J.M., and Juriaanse, A.C. (1988). Food Microstruct. 7: 189–193.
- 223De Bruijne, P., Van Eendendurg, J., and Juman, H.J. (1993). Automated process for the preparation of an edible fat-containing product and apparatus for carrying out such a process. European Patent 0,341,771B2 (3 March 1993), (to Unilever).
- 224Kattenberg, H.R. (1977). Plastic fat product. U.S. Patent 4,055,679 (25 October 1977), (to Lever Brothers Co.).
- 225Wilson, A.D., Oakley, H.B., and Rouke, J. (1952). Method of making margarine and the resulting product. U.S. Patent 2,592,224 (8 April 1952), (to Lever Brothers Co.).
- 226Miller, B.D.H., Phelps, P. and Bevarly, H.W. (1943). Preparation of emulsions. U.S. Patent 2,330,986 (5 October 1943), (to Girdler Corp.).
- 227Terada, K., Fujita, S., Kohno, H. et al. (1975). Edible oil in water in oil emulsion. U.S. Patent 3,917,859 (4 November 1975), (to Adeka Corp.).
- 228Gander, K.F. (1970). Process for preparing margarine, etc. U.S. Patent 3,488,199 (6 January 1970), (to Lever Brothers Co.).
- 229Moran, D.P.J. (1970). Fatty emulsions and their preparation. U.S. Patent 3,490,919 (20 January 1970), (to Lever Brothers Co.).
- 230Cramer, G.C. (1982). Filled cream, butter-like product made therefrom and method of manufacturing them. U.S. Patent 4,315,955 (16 February 1982), (to Madison Creamery Inc.).
- 231Price, R.D. and Sledzieski, W.L. (1988). Margarine products or spreads and method for their manufacture. European Patent 0,139,398B1 (27 April 1988), (to Nabisco Brands Inc.).
- 232Brockhus, J.J., Schnell, D., and Vermaat, K.T. (1992). Cream, churned product made therefrom and method of manufacturing them. European Patent 0,505,007B1 (15 November 1992), (to Unilever).
- 233Bouffard, C. (1974). Rev. Fr. Corps Gras 21: 351–357.
- 234Faur, L. (1980). Rev. Fr. Corps Gras 27: 319.
- 235Pichel, M.J. (1967). Fluid margarine emulsion stabilized by hard fat. U.S. Patent 3,338,720 (29 August 1967), (to Carlin Foods, Corp.).
- 236Melnick, D. and Josefowicz, E.L. (1969). Process for preparing liquid margarine. U.S. Patent 3,472,661 (14 October 1969), (to Unilever).
- 237Wilton, I. (1972). Pourable margarine. U.S. Patent 3,682,656 (8 August 1972), (to Margarinbolaget AB).
- 238Kahuda, Y., Brampton, A., and Jahan-Aval, F. (2003). Process for preparing high liquid oil margarine. U.S. Patent Application 2003016193 (28 August 2003).
- 239Moran, D.P.J. (1993). Porium Technol., No. 15, Palm Oil Research Institute of Malaysia, February 1993.
- 240Madsen, J. (1990). In: World Conference Proceedings, Edible Fats and Oils Processing: Basic Principles and Modern Practices (ed. D. Erickson), 221–227. Champaign, IL: American Oil Chemists' Society.
- 241Altrock, W. and Ritums, J.A. (1982). Process for producing a low-fat oil-in-water-in-oil emulsion. U.S. Patent 4,366,180 (28 December 1982), (to Lever Brothers Co.).
- 242Josefowicz, E.L., Cooper, I., and Melnick, D. (1969). Low-fat table spread compositions. U.S. Patent 3,457,086 (22 July 1969), (to Unilever).
- 243Spritzer, J.G., Kearns, J.J., and Owen, C. (1967). Method for production of low-calorie margarine substitute products. U.S. Patent 3,360,377 (26 December 1967), (to J.G. Spritzer et al.).
- 244Linteris, L.L. (1971). Low calorie pourable spread. Canadian Patent 871,647 (25 May 1971), (to Unilever).
- 245Norton, I.T. (1993). Fat-containing dispersion and method of preparing such dispersion. U.S. Patent 5,244,688 (14 September 1993), (to Van den Bergh Foods Co.).
- 246Norton, I.T. and Underdown, J. (1994). Water-in-oil dispersion and process for preparing such dispersion. U.S. Patent 5,306,517 (26 April 1994), (to Van den Bergh Foods Co.).
- 247Ernsting, P.B. (1989). Process for preparing an edible dispersion. U.S. Patent 4,883,681 (28 November 1989), (to Lever Brothers Co.).
- 248Sreenivasan, B. and Simpson, E.A. (1989). Process for producing low fat spreads by phase inversion. U.S. Patent 4,849,243 (18 July 1989), (to Lever Brothers Co.).
- 249Norton, I.T. and Underdown, J. (1992). Water-in-oil dispersion and process for preparing such dispersion. U.S. Patent 5,151,290 (29 September 1992), (to Van den Bergh Foods Co.).
- 250Milo, B. and Ochmann, R. (1993). Process for spread production and apparatus for performance of the process. European Patent 0,396,170B1 (28 July 1993), (to Unilever).
- 251Madsen, S. (1991). Res. Discl. (330): 774.
- 252Norton, I.T. and Brown, C.R.T. (1987). Edible dispersion. European Patent 0,271,132B1 (15 January 1987), (to Unilever).
- 253Norton, I.T. (1994). Water-in-oil dispersion. European Patent 0,474,299B1 (31 August 1994), (to Unilever).
- 254Pettitt, D.J., Gibson, W., and Challen, I.A. (1989). Res. Discl. (301): 338.
- 255Cain, F.W., Jones, M.G., and Nortan, I.T. (1990). Water-in-oil emulsion spread. U.S. Patent 4,917,915 (17 April 1990), (to Lever Brothers Co.).
- 256Morehouse, A.L. and Lewis, C.J. (1985). Low fat spread. U.S. Patent 4,536,408 (20 August 1985), (to Grain Processing Corp.).
- 257Norton, I.T. and Livingston, R.M. (1996). Edible spread. European Patent 0,496,466B2 (23 October 1996), (to Unilever).
- 258Jones, M.G. and Norton, I.T. (1993). Water-and-oil emulsion and process for preparing such emulsion. U.S. Patent 5,217,742 (8 June 1993), (to Van den Bergh Foods Co.).
- 259Bosco, P.M. and Sledzieski, W.L. (1981). Low-fat, butter-flavored spread and process. U.S. Patent 4,279,941 (21 July 1981) and 4,292,333 (29 September 1981), (to Standard Brands Inc.).
- 260Miller, D.E. and Werstak, C.E. (1980). Low-fat comestible spread substitutes. U.S. Patent 4,238,520 (9 December 1980), (to Durkee Industrial Foods Corp.).
- 261Darling, D.F. (1984). Process for producing a spreadable emulsion. U.S. Patent 4,443,487 (17 April 1984), (to Lever Brothers Co.).
- 262Cain, F.W., Clark, A.H., Dunphy, P.J. et al. (1990). Edible plastic dispersion. U.S. Patent 4,956,193 (11 September 1990), (to Lever Brothers Co.).
- 263Wesdorp, L.H., Madisen, R.A., Kasica, J. et al. (1994). Edible plastic dispersion having a rapid gel-setting starch. U.S. Patent 5,279,844 (18 January 1994), (to Van den Bergh Foods Co.).
- 264Banach, G., Wesdorp, L.H., and Fiori, F.S. (1993). Process of preparing an extra lowfat spread. U.S. Patent 5,252,352 (12 October 1993), (to Van den Bergh Foods Co.).
- 265Heertje, I. and Wesdorp, L.H. (1993). Low fat spreads and dressings. European Patent Application 0,547,647A1 (23 June 1993), (to Unilever).
- 266Sundram, K., Perlman, D., and Hayes, K.C. (2003). Increasing the HDL level and the HDL/LDL ratio in human serum by balancing saturated and polyunsaturated dietary fatty acids. U.S. Patent 6,630,192 (7 October 2003), (to Brandeis University).
- 267McBride, R.L. and Richardson, K.C. (1983). Lebensm. Wiss. Technol. 16: 198–199.
- 268Naudet, M. and Biasini, S. (1976). Rev. Fr. Corps Gras 23: 337.
- 269Maskan, M., Öner, M.D., and Aya, A.K. (1993). J. Food Qual. 16: 175–186.
- 270Segura, J.A., Herrera, M.L., and Anon, M.C. (1990). J. Am. Oil Chem. Soc. 67: 989–992.
- 271Entz, R.C. and Diachenko, G.W. (1988). Food Addit. Contam. 5: 267–276.
- 272Princen, H.M. and Aronson, M.P. (1979). Method for reducing the surface discoloration of food spreads and food spreads produced thereby. U.S. Patent 4,176,200 (27 November 1979), (to Lever Brothers Co.).
- 273Havenstein, A.G., Kahle, W., and Schnell, D. (1987). Package containing a w/o fat dispersion and process for producing the same. European Patent 0,240,089 B1 (31 January 1987), (to Unilever).
- 274Poot, C. and Verburg, C.C. (1974). Fette Seifen Anstrichm. 76: 178–181.
- 275Josefowicz, E.L. and Melnick, D. (1964). Process for wrapping margarine and butter. U.S. Patent 3,148,993 (15 September 1964), (to Unilever).
- 276Barnes, P. (1989). Lipid Technol. 1: 46–47.
- 277Mossel, D.A.A. (1969). in Margarine Today: Technological and Nutritional Aspects, Symposium, Dijon, France, March 21, 1969, pp. 104–125.
- 278Faur, L. (1980). Rev. Fr. Corps Gras 27: 371.
- 279Dritschel, M.E. (1970). Food Eng. 42 (10): 90.