The crystal structure of the new orthrhombic ternary boride MgNiB₄ has been determined by the single-crystal method. The MgNiB₄ structure type represents the structure family based on AlB₂ and YCrB₄.

The title three-dimensional cobalt(II) coordination polymer features a three-dimensional architecture and exhibits a significant third-order nonlinear optical absorption effect.

The rich redox chemistry of tetraoxolene ligands is harnessed to synthesize a family of bimetallic complexes with phenyl-substituted bridging tetraoxolene and terminal tris[(pyridin-2-yl)methyl]amine ligands.

Aminocarb, a synthetic pesticide, was crystallized and characterized by single-crystal and powder X-ray diffraction. The structural stability and intermolecular interactions were investigated using differential scanning calorimetry (DSC) and density functional theory (DFT). The results show that the compound is chemically stable, and the two dominating interactions are electrostatic and dispersion energies.

The crystal structure of the new azo compound methyl 2-{2-[(E)-2-oxo-1,2-dihydronaphthalen-1-ylidene]hydrazin-1-yl}benzoate was determined by X-ray diffraction at 173 K. The asymmetric unit is represented in its hydrazoic form. The determined structure has a naphthone and a hydrazinylidene group and adopts an E conformation with respect to the hydrazo group. Each molecule has an intramolecular N—H…O hydrogen bond in the crystal.

The crystal structure of Ca(BF₄)₂·xH₂O has been solved ab initio and refined from laboratory powder diffraction data. The water molecules all belong to [CaO₄F₄] square antiprisms sharing F corners with [BF₄] tetrahedra, forming a mono-dimensional structure of infinite ribbons interconnected by H…F and H…O hydrogen bonds.

The crystal structure of a new 2D perovskite (n = 1), NaAl(SO₄)F₂, has been solved ab initio and refined from laboratory powder diffraction data.

The high-pressure crystal structure of n-hexylamine remains isostructural with its low-temperature phase. The compressibility of the N—H…N hydrogen bonds has been analyzed in relation to the shortest C—H…N and H…H intermolecular distances.

Hydrothermal self-assembly between Zn(NO₃)₂·6H₂O and trans-1,2-bis(pyridin-3-yl)ethylene with two similar dicarboxylic acids affords two different Zn^II coordination polymers. These coordination polymers exhibit 3D and 2D networks with distinct topologies.

The crystal structure of a coplanar Schiff base, synthesized via solventless maceration, was determined using X-ray diffraction and analyzed with Hirshfeld surface and QTAIM-C calculations to elucidate intermolecular interactions.