• Issue

    Applied Organometallic Chemistry: Volume 29, Issue 1

    i-iii, 1-61
    January 2015

Issue Information

Issue Information

  • Pages: i-iii
  • First Published: 15 December 2014

Full Papers

Polyaniline-anchored palladium catalyst-mediated Mizoroki–Heck and Suzuki–Miyaura reactions and one-pot Wittig–Heck and Wittig–Suzuki reactions

  • Pages: 1-6
  • First Published: 06 November 2014
Polyaniline-anchored palladium catalyst-mediated Mizoroki–Heck and Suzuki–Miyaura reactions and one-pot Wittig–Heck and Wittig–Suzuki reactions

A polyaniline-anchored palladium heterogeneous catalyst was prepared and screened for coupling reactions of aryl halides. The robust, recyclable catalyst was effective in Mizoroki–Heck and Suzuki–Miyaura reactions of aryl bromides and iodides. The catalyst system was further employed for one-pot Wittig–Heck and Wittig–Suzuki combinations to obtain conjugated compounds in good conversions.

Comparison between various Keggin and Wells–Dawson sandwich-type polyoxometalates in catalytic oxidation of cyclooctene and cyclohexene with hydrogen peroxide

  • Pages: 7-11
  • First Published: 23 October 2014
Comparison between various Keggin and Wells–Dawson sandwich-type polyoxometalates in catalytic oxidation of cyclooctene and cyclohexene with hydrogen peroxide

Tetra-n-butylammonium salts of [M4(PW9O34)2]m and [M4(P2W15O56)2]n were used as effective catalysts for the oxidation of cyclooctene and cyclohexene under various conditions. Wells–Dawson-type polyoxometalates were less active than Keggin ones. Higher conversions were obtained with Zn- and slightly lower with Fe-substituted polyoxometalates of both sandwich-type compounds.

Metal–organic framework MIL-125(Ti) for efficient adsorptive removal of Rhodamine B from aqueous solution

  • Pages: 12-19
  • First Published: 23 October 2014
Metal–organic framework MIL-125(Ti) for efficient adsorptive removal of Rhodamine B from aqueous solution

A metal–organic framework material, MIL-125(Ti), was solvothermally prepared and characterized, and was then used as an adsorbent for Rhodamine B removal in aqueous solution.

Binuclear dichlorido(η6-p-cymene)ruthenium(II) complexes with bis(nicotinate)- and bis(isonicotinate)-polyethylene glycol ester ligands

  • Pages: 20-25
  • First Published: 06 November 2014
Binuclear dichlorido(η6-p-cymene)ruthenium(II) complexes with bis(nicotinate)- and bis(isonicotinate)-polyethylene glycol ester ligands

Neutral binuclear and mononuclear ruthenium complexes with bis(nicotinate)- or bis(isonicotinate)-polyethylene glycol esters and ethylene glycol monomethyl ether nicotinate, respectively, were synthesized and characterized. Stability of the binuclear complexes in the presence of DMSO was studied, as well as the formation of a cationic complex. Ligand precursors and ruthenium(II) complexes were tested for their in vitro cytotoxicity against five tumour cell lines.

Green and effective route for the synthesis of monodispersed palladium nanoparticles using herbal tea extract (Stachys lavandulifolia) as reductant, stabilizer and capping agent, and their application as homogeneous and reusable catalyst in Suzuki coupling reactions in water

  • Pages: 26-32
  • First Published: 17 November 2014
Green and effective route for the synthesis of monodispersed palladium nanoparticles using herbal tea extract (Stachys lavandulifolia) as reductant, stabilizer and capping agent, and their application as homogeneous and reusable catalyst in Suzuki coupling reactions in water

A simple and green synthesis of palladium nanoparticles, using the aqueous extract of herbal tea (Stachys lavandulifolia) has been described. Moreover, the Pd-NPs stabilized by S. lavandulifolia extract were applied in the Suzuki cross-coupling reactions in water at mild conditions.

Palladium nanoparticles supported on cucurbit[6]uril: an efficient heterogeneous catalyst for the Suzuki reaction under mild conditions

  • Pages: 33-39
  • First Published: 02 December 2014
Palladium nanoparticles supported on cucurbit[6]uril: an efficient heterogeneous catalyst for the Suzuki reaction under mild conditions

Palladium nanoparticles supported on cucurbit[6]uril are an efficient and recyclable catalyst for Suzuki reactions of various aryl halides with arylboronic acids under mild conditions. These reactions were carried out in EtOH–H2O mixture in the presence of 0.05 mol% Pd(0).

Pd(II) salen complex covalently anchored to multi-walled carbon nanotubes as a heterogeneous and reusable precatalyst for Mizoroki–Heck and Hiyama cross-coupling reactions

  • Pages: 40-44
  • First Published: 19 November 2014
Pd(II) salen complex covalently anchored to multi-walled carbon nanotubes as a heterogeneous and reusable precatalyst for Mizoroki–Heck and Hiyama cross-coupling reactions

A heterogeneous Pd(II) salen complex anchored to multi-walled carbon nanotubes (Pd-Salen@MWCNTs) was used as a catalyst for Heck and Hiyama couplings.

Iron phthalocyanine as new efficient catalyst for catalytic transfer hydrogenation of simple aldehydes and ketones

  • Pages: 45-49
  • First Published: 17 November 2014
Iron phthalocyanine as new efficient catalyst for catalytic transfer hydrogenation of simple aldehydes and ketones

CTH reaction of differently substituted aldehydes and ketones were studied using iron phthalocyanine catalyst, in order to alternate the typically used rare transition metals (Ir, Rh, Ru) by easily available and less expensive metal. During this study iron phthalocyanine was proven to be an efficient hydrogenation catalyst and the anchored version of it was also prepared. The immobilized iron phthalocyanine showed similar activity in CTH reaction of carbonyl compounds and it was easy to handle and possible to recycle.

One-pot synthesis of polyfluoroterphenyls via palladium-catalyzed Suzuki–Miyaura coupling of chlorobromobenzene and CH bond functionalization of perfluoroarenes

  • Pages: 50-56
  • First Published: 17 November 2014
One-pot synthesis of polyfluoroterphenyls via palladium-catalyzed Suzuki–Miyaura coupling of chlorobromobenzene and C<span class='icomoon'></span>H bond functionalization of perfluoroarenes

An efficient tandem route for the synthesis of polyfluoroterphenyl derivatives has been developed using Pd-catalyzed three-component coupling reaction involving direct CH activation of perfluoroarenes.