Comparison between various Keggin and Wells–Dawson sandwich-type polyoxometalates in catalytic oxidation of cyclooctene and cyclohexene with hydrogen peroxide
Mostafa Riahi Farsani
Department of Chemistry, University of Isfahan, Isfahan, 81746-73441 Iran
Search for more papers by this authorFariba Jalilian
Department of Chemistry, University of Isfahan, Isfahan, 81746-73441 Iran
Search for more papers by this authorCorresponding Author
Bahram Yadollahi
Department of Chemistry, University of Isfahan, Isfahan, 81746-73441 Iran
Correspondence to: Bahram Yadollahi, Department of Chemistry, University of Isfahan, Isfahan 81746-73441, Iran. E-mail: [email protected]Search for more papers by this authorHadi Amiri Rudbari
Department of Chemistry, University of Isfahan, Isfahan, 81746-73441 Iran
Search for more papers by this authorMostafa Riahi Farsani
Department of Chemistry, University of Isfahan, Isfahan, 81746-73441 Iran
Search for more papers by this authorFariba Jalilian
Department of Chemistry, University of Isfahan, Isfahan, 81746-73441 Iran
Search for more papers by this authorCorresponding Author
Bahram Yadollahi
Department of Chemistry, University of Isfahan, Isfahan, 81746-73441 Iran
Correspondence to: Bahram Yadollahi, Department of Chemistry, University of Isfahan, Isfahan 81746-73441, Iran. E-mail: [email protected]Search for more papers by this authorHadi Amiri Rudbari
Department of Chemistry, University of Isfahan, Isfahan, 81746-73441 Iran
Search for more papers by this authorAbstract
The catalytic performance of tetra-n-butylammonium salts of Keggin and Wells–Dawson sandwich-type polyoxotungstates, [M4(PW9O34)2]m− and [M4(P2W15O56)2]n− (M = Mn2+, Fe3+, Co2+, Ni2+, Zn2+), in the oxidation of cyclooctene and cyclohexene with 30% hydrogen peroxide under various conditions was investigated. In comparison, Wells–Dawson sandwich-type polyoxometalates were found to be less active than Keggin ones. In both of them, those containing Zn and Fe gave higher conversions for different oxidation conditions. These catalysts showed very good reusability in the oxidation reaction. Copyright © 2014 John Wiley & Sons, Ltd.
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