Volume 58, Issue 12 pp. o1405-o1407

(rac-5RS,7RS,8SR)-Spiro­[7-methoxy­carbonyl-1-aza-3-thia­bi­cyclo­[3.3.0]­octane-8,1′-ace­naphthyl­en]-2′-one

First published: 29 July 2004
V. Parthasarathi, e-mail: [email protected]

Abstract

The title compound, C19H17NO3S, crystallizes in the monoclinic space group P21/c, with four mol­ecules in the unit cell. The structure contains a spiro-carbon connecting a bi­cyclo-octane group, consisting of two fused five-membered rings, to an ace­naphthyl­ene moiety. The five-membered ring containing the S atom is in an envelope conformation. The conformation of the other five-membered ring of the bi­cyclo-octane moiety is close to a half-chair. The methoxycarbonyl group is equatorially substituted.

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