Volume 56, Issue 6 pp. 705-707

2-(1,3-Dithian-2-yl)benzaldehyde and N-{2-[2-(1,3-dioxan-2-yl)phenoxy]­ethyl}phthalimide

Paul G. Jene

Paul G. Jene

Department of Chemistry, Northwestern University, 2145 Sheridan Rd., Evanston, IL 60208-3113, USA

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James A. Ibers

James A. Ibers

Department of Chemistry, Northwestern University, 2145 Sheridan Rd., Evanston, IL 60208-3113, USA

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First published: 30 June 2004
James A. Ibers, e-mail: [email protected]

Abstract

The crystal structures of two elaborated-porphyrin precursors have been determined. In the crystalline state, 2-(1,3-di­thian-2-yl)­benz­aldehyde, C11H12OS2, has its di­thiane ring in a slightly distorted chair conformation. The mol­ecules pack in anti-parallel chains. N-{2-[2-(1,3-Dioxan-2-yl)­phenoxy]­ethyl}­phthal­imide, C20H19NO5, is in a folded conformation. The dihedral angle between the phthal­imide and phenyl planes is 80.07 (3)°. In the crystalline states, mol­ecules stack on top of one another.

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