Modulating the Rotation of a Molecular Rotor through Hydrogen-Bonding Interactions between the Rotator and Stator†
Qian-Chong Zhang
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
Search for more papers by this authorFang-Ting Wu
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
Search for more papers by this authorHui-Min Hao
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
Search for more papers by this authorHang Xu
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
Search for more papers by this authorCorresponding Author
Hai-Xia Zhao
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)Search for more papers by this authorCorresponding Author
Prof. Dr. La-Sheng Long
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)Search for more papers by this authorProf. Rong-Bin Huang
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
Search for more papers by this authorProf. Dr. Lan-Sun Zheng
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
Search for more papers by this authorQian-Chong Zhang
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
Search for more papers by this authorFang-Ting Wu
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
Search for more papers by this authorHui-Min Hao
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
Search for more papers by this authorHang Xu
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
Search for more papers by this authorCorresponding Author
Hai-Xia Zhao
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)Search for more papers by this authorCorresponding Author
Prof. Dr. La-Sheng Long
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)Search for more papers by this authorProf. Rong-Bin Huang
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
Search for more papers by this authorProf. Dr. Lan-Sun Zheng
State Key Laboratory of Physical Chemistry of Solid Surfaces and the Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
Search for more papers by this authorThis work was supported by the 973 project from MSTC (grant number 2012CB821704) and The NNSFC (grant numbers 20825103, 90922031, 21001089, and 21021061).
Graphical Abstract
Two molecular rotors were synthesized (see picture). An investigation of the rotator rotation based on the imaginary parts of the complex dielectric constant (ε′′) for each molecular rotor at various frequencies and temperatures revealed that the rotation of the mono-component molecular rotor could be modulated through hydrogen-bonding interactions between the rotator and the stator.
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