Crystal Engineering of a Microporous, Catalytically Active fcu Topology MOF Using a Custom-Designed Metalloporphyrin Linker†
Le Meng
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/
Search for more papers by this authorQigan Cheng
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/
Search for more papers by this authorChungsik Kim
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/
Search for more papers by this authorWen-Yang Gao
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/
Search for more papers by this authorLukasz Wojtas
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/
Search for more papers by this authorYu-Sheng Chen
ChemMatCARS, Center for Advanced Radiation Sources, the University of Chicago, 9700 S. Cass Avenue, Argonne, IL 60439 (USA)
Search for more papers by this authorCorresponding Author
Prof. Michael J. Zaworotko
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/Search for more papers by this authorCorresponding Author
Prof. X. Peter Zhang
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/Search for more papers by this authorCorresponding Author
Prof. Shengqian Ma
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/Search for more papers by this authorLe Meng
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/
Search for more papers by this authorQigan Cheng
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/
Search for more papers by this authorChungsik Kim
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/
Search for more papers by this authorWen-Yang Gao
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/
Search for more papers by this authorLukasz Wojtas
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/
Search for more papers by this authorYu-Sheng Chen
ChemMatCARS, Center for Advanced Radiation Sources, the University of Chicago, 9700 S. Cass Avenue, Argonne, IL 60439 (USA)
Search for more papers by this authorCorresponding Author
Prof. Michael J. Zaworotko
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/Search for more papers by this authorCorresponding Author
Prof. X. Peter Zhang
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/Search for more papers by this authorCorresponding Author
Prof. Shengqian Ma
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620 (USA) http://sqma.myweb.usf.edu/Search for more papers by this authorThe authors acknowledge the University of South Florida and the US Department of Energy (DE-AR0000177) for financial for financial support of this work. The authors thank Dr. Daqiang Yuan for help in drawing structural pictures of MMPF-3. The crystal diffraction of MMPF-3 was carried out at the Advanced Photon Source on beamline 15ID-B of ChemMatCARS Sector 15 (NSF/CHE-0822838, DE-AC02-06CH11357).
Graphical Abstract
A 12-connected fcu metal–organic framework (MOF), MMPF-3, has been prepared using a CoII metalloporphyrin. MMPF-3 is comprised of the same polyhedral supermolecular building blocks as the prototypal fcu-MOF, fcu-MOF-1, and its nanoscale cavities feature 18 catalytically active cobalt centers. The high density (ca. 5 cobalt sites/nm3) affords MMPF-3 superior performance in catalytic epoxidation of trans-stilbene compared to other MOFs.
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