Volume 60, Issue 5 pp. m690-m692

Di-μ-phenyl­methane­thiol­ato-μ-sulfido-bis­[carbonyl(η5-cyclo­penta­dienyl)molybdenum(III)]

Richard Chee Seng Wong

Richard Chee Seng Wong

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia

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Mei Lee Ooi

Mei Lee Ooi

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia

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Seik Weng Ng

Seik Weng Ng

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia

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First published: 14 May 2004
Seik Weng Ng, e-mail: [email protected]

Abstract

The reaction of bis­[cyclo­penta­dienyl­tri­carbonyl­molyb­den­um(I)] with di­benzyl tri­sulfide affords the title compound, [Mo2S(C5H5)2(C7H7S)2(CO)2], as one of the products. Three independent mol­ecules exist in the asymmetric unit of the triclinic unit cell; one is related to another by a false inversion center and is related to the third by a false translation. In each dinuclear entity, each Mo atom is bonded to a cyclo­penta­dienyl anion and a carbon monoxide mol­ecule; the phenyl­methane­thiol­ate groups bridge a pair of Mo atoms, as does the sulfide atom.

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