5-(2-Chlorophenyl)-2-p-tolyl-1,3,4-thiadiazole
Abstract
The title compound, C15H11ClN2S, has been prepared by the reaction of Lawesson's reagent with N-(2-chlorobenzoyl)-N′-(4-methylbenzoyl)hydrazine, under microwave irradiation and in the absence of solvent. It crystallizes with two molecules per asymmetric unit and X-ray analysis reveals that the three rings in both molecules are nearly coplanar. The molecules form stacks, in a head-to-tail manner, with intermolecular π–π interactions. Intermolecular C—H⋯N hydrogen bonds are also present.