Volume 60, Issue 5 pp. o881-o883

5-(2-Chloro­phenyl)-2-p-tolyl-1,3,4-thia­diazo­le

Hua-Ming Huang

Hua-Ming Huang

Department of Chemistry, Nankai University, Tianjin 300071, People's Republic of China

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Hai-Tao Yu

Hai-Tao Yu

Department of Chemistry, Nankai University, Tianjin 300071, People's Republic of China

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Pei-Li Chen

Pei-Li Chen

Department of Chemistry, Nankai University, Tianjin 300071, People's Republic of China

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Ji-Ben Meng

Ji-Ben Meng

Department of Chemistry, Nankai University, Tianjin 300071, People's Republic of China

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First published: 14 May 2004
Ji-Ben Meng, e-mail: [email protected]

Abstract

The title compound, C15H11ClN2S, has been prepared by the reaction of Lawesson's reagent with N-(2-chloro­benzoyl)-N′-(4-methyl­benzoyl)­hydrazine, under microwave irradiation and in the absence of solvent. It crystallizes with two mol­ecules per asymmetric unit and X-ray analysis reveals that the three rings in both mol­ecules are nearly coplanar. The mol­ecules form stacks, in a head-to-tail manner, with intermolecular π–π interactions. Intermolecular C—H⋯N hydrogen bonds are also present.

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