Volume 60, Issue 5 pp. m647-m649

Polymeric bis­(hydrogen pyrazine-2,3-di­carboxyl­ato)copper(II) N,N′-di­methyl­form­amide disolvate

First published: 14 May 2004
Hong-Ping Xiao, e-mail: [email protected]

Abstract

In the title compound, {[Cu(C6H3N2O4)2]·2C3H7NO}n, each copper(II) center is surrounded by two N atoms, two bridging carboxyl­ate O atoms from two pyrazine-2,3-di­carboxyl­ate anions, and two bridging carboxyl­ate O atoms of two pyrazine-2,3-di­carboxyl­ate anions from neighboring units, forming an elongated CuN2O4 octahedron. The [Cu(C6H3N2O4)2] blocks, with the copper(II) cation located on a center of inversion, are connected together by four μ-carboxyl­ate bridges, creating a one-dimensional intersecting double chain.

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