Volume 60, Issue 5 pp. m657-m658

Bis­[bis(2-pyridyl)­methanediol-κ3N,N′,O]copper(II) bis­(adamantane-1-carboxyl­ate)

Ming-Liang Tong

Ming-Liang Tong

School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People's Republic of China

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Ai-Ju Zhou

Ai-Ju Zhou

School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People's Republic of China

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Sheng Hu

Sheng Hu

School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People's Republic of China

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First published: 14 May 2004
Citations: 1
Ming-Liang Tong, e-mail: [email protected]

Abstract

Di-2-pyridyl ketone reacts with copper(II) nitrate and sodium adamantane-1-carboxyl­ate in aceto­nitrile–water to form bis­[bis(2-pyridyl)­methanediol]copper(II) bis­(adamantane-1-carboxyl­ate), [Cu(C11H10N2O2)2](C11H15O2)2. The Cu atom in this dicationic complex occupies a special position at an inversion centre and has a tetragonally distorted octahedral coordination, formed by four `normal' Cu—N [2.0114 (16) and 2.0155 (16) Å] and two `long' Cu—O bonds [2.3690 (14) Å]. The methanediol hydroxyl groups are hydrogen-bonded to the adamantane-1-carboxyl­ate anions.

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