Bis[bis(2-pyridyl)methanediol-κ3N,N′,O]copper(II) bis(adamantane-1-carboxylate)
Abstract
Di-2-pyridyl ketone reacts with copper(II) nitrate and sodium adamantane-1-carboxylate in acetonitrile–water to form bis[bis(2-pyridyl)methanediol]copper(II) bis(adamantane-1-carboxylate), [Cu(C11H10N2O2)2](C11H15O2)2. The Cu atom in this dicationic complex occupies a special position at an inversion centre and has a tetragonally distorted octahedral coordination, formed by four `normal' Cu—N [2.0114 (16) and 2.0155 (16) Å] and two `long' Cu—O bonds [2.3690 (14) Å]. The methanediol hydroxyl groups are hydrogen-bonded to the adamantane-1-carboxylate anions.