Volume 60, Issue 5 pp. m634-m636

A nickel(II) complex of an unsymmetrical tetradentate Schiff base

Bixue Zhu

Bixue Zhu

Department of Chemistry, Nankai University, Tianjin 300071, People's Republic of China

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Wenjuan Ruang

Wenjuan Ruang

Department of Chemistry, Nankai University, Tianjin 300071, People's Republic of China

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Zhiang Zhu

Zhiang Zhu

Department of Chemistry, Nankai University, Tianjin 300071, People's Republic of China

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First published: 14 May 2004
Zhiang Zhu, e-mail: [email protected]

Abstract

The structure of the title nickel(II) complex, (2-{2-[α-(5-chloro-2-oxido­phenyl)­benzyl­idene­amino]­phenyl­imino­methyl}-5-hydroxy­phenolato)­nickel(II) methanol disolvate, [Ni(C26H17ClN2O3)]·2CH3OH, containing an unsymmetrical tetradentate schiff base, comprises two neutral [Ni(CBP-PHEN-4-OHSAL)] complex mol­ecules and four methanol solvent mol­ecules in the asymmetric unit. Each NiII center exists in a four-coordinate square-planar geometry defined by an N2O2 donor set.

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