Volume 60, Issue 5 pp. m625-m627

μ-1,2-Bis­(di­cyclo­hexyl­phosphino)­ethane-κ2P:P′-bis{[1,2-bis­(di­cyclo­hexyl­phosphino)­ethane-κ2P,P′]­palladium(0)}

Robert C. Boyle

Robert C. Boyle

Department of Chemistry, Tulane University, New Orleans, LA 70118, USA

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Joel T. Mague

Joel T. Mague

Department of Chemistry, Tulane University, New Orleans, LA 70118, USA

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Mark J. Fink

Mark J. Fink

Department of Chemistry, Tulane University, New Orleans, LA 70118, USA

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First published: 14 May 2004
Joel T. Mague, e-mail: [email protected]

Abstract

The title compound, [Pd2(C26H48P2)3], crystallizes in an `extended' conformation with crystallographically imposed centrosymmetry. The crystal used was twinned via a 180° rotation about the reciprocal axis (0,0,1). The ratio of the two twin components is 54.16 (4):46.84 (4). The crystal packing involves significant interdigitation of the cyclo­hexyl groups with a considerable number of short H⋯H contacts.

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