Benzyltrimethylammonium tris(pyrimidine-2-thiolato-κ2N,S)nickelate(II)
First published: 14 May 2004
Mao-Chun Hong, e-mail: [email protected]
Abstract
The title compound, cis-[C6H5CH2N(CH3)3][Ni(pymt)3], (pymt = pyrimidine-2-thiolate, C4H3N2S) consists of discrete cations and anions. The coordination geometry around nickel is highly distorted octahedral due to the presence of three four-membered N,S-chelate rings in a cis configuration. The Ni—S distances are in the range 2.4617 (5)–2.5290 (5) Å and the Ni—N bond distances range from 2.0490 (14) to 2.0689 (14) Å.
