Volume 60, Issue 5 pp. m551-m553

Bromo­propyl­di­carbonyl­(η5-penta­methyl­cyclo­penta­dienyl)­iron(II)

Holger B. Friedrich

Holger B. Friedrich

School of Pure and Applied Chemistry, University of KwaZulu-Natal, Howard College Campus, Durban, 4041, South Africa

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Martin O. Onani

Martin O. Onani

School of Pure and Applied Chemistry, University of KwaZulu-Natal, Howard College Campus, Durban, 4041, South Africa

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Melanie Rademeyer

Melanie Rademeyer

School of Pure and Applied Chemistry, University of KwaZulu-Natal, Howard College Campus, Durban, 4041, South Africa

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First published: 14 May 2004
Citations: 1
Melanie Rademeyer, e-mail: [email protected]

Abstract

In Cp*Fe(CO)2(n-C3H6Br), where Cp* = η5-C5(CH3)5, the Fe atom is coordinated by a penta­methyl­cyclo­penta­dienyl ligand, two carbonyl ligands and a bromo­alkyl chain in a pseudo-octahedral arrangement. The molecular geometry is similar to that reported for a related structure, with the alkyl chain in an all-trans conformation and a Fe—C(alkyl) bond length of 2.057 (3) Å. In the crystal structure, the mol­ecules pack in layers.

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