Bis[μ-bis(diphenylphosphino)amine-κP:P′]bis[acetonitrilesilver(I)] tris(cis-1,2-dicyanoethylene-1,2-dithiolate)molybdate(IV)
Abstract
The reaction between the metal diphosphine [Ag2(dppa)2](BF4)2 [dppa is bis(diphenylphosphino)amine, C24H21N2P2] and the metal thiolate [Bu4N]2[Mo(mnt)3] (mnt is cis-1,2-dicyanoethylene-1,2-dithiolate, C4N2S2) gave the title compound, [Ag2(dppa)2(MeCN)2][Mo(mnt)3]. The Ag⋯Ag distance of 2.9501 (13) Å is shorter than the sum of van der Waals radii for two Ag atoms, indicating a weak metal–metal contact in the complex. The cation lies on an inversion centre and the anion lies on a twofold axis.