Volume 58, Issue 11 pp. m631-m633

Bis­[μ-bis­(di­phenyl­phosphino)­amine-κP:P′]­bis­[aceto­nitrile­silver(I)] tris(cis-1,2-di­cyano­ethyl­ene-1,2-di­thiol­ate)­molybdate(IV)

First published: 29 July 2004
Zhong-Ning Chen, e-mail: [email protected]

Abstract

The reaction between the metal diphosphine [Ag2(dppa)2](BF4)2 [dppa is bis­(di­phenyl­phosphino)­amine, C24H21N2P2] and the metal thiol­ate [Bu4N]2[Mo(mnt)3] (mnt is cis-1,2-di­cyano­ethyl­ene-1,2-di­thiol­ate, C4N2S2) gave the title compound, [Ag2(dppa)2(MeCN)2][Mo(mnt)3]. The Ag⋯Ag distance of 2.9501 (13) Å is shorter than the sum of van der Waals radii for two Ag atoms, indicating a weak metal–metal contact in the complex. The cation lies on an inversion centre and the anion lies on a twofold axis.

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