Volume 58, Issue 11 pp. o1220-o1221

5,8-Bis­(tri­methyl­silyl­ethynyl)­quinoline

First published: 29 July 2004
Louise Male, e-mail: [email protected]

Abstract

The title compound, C19H23NSi2, is a TMS-protected rigid-rod di-yne. It is useful as a model compound for organometallic species of which it is a precursor and, like them, exhibits π-conjugation through the heteroaromatic linker unit in the backbone. The mol­ecule is pseudo-linear, with a planar central quinoline group. Two C—H⋯N short intermolecular contacts are found, with C⋯N distances of 3.483 (5) and 3.671 (6) Å. An intermolecular contact between an aromatic H atom and the C[triple-bond]C triple bond is also observed.

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