Volume 58, Issue 11 pp. o1182-o1184

1,5-Di­methyl-4-{[(E)-3-oxo-3-(2-thienyl)-1-(tri­fluoro­methyl)-1-propenyl]­amino}-2-phenyl-1,2-di­hydro-3H-pyrazol-3-one

First published: 29 July 2004
Jin-Ling Wang, e-mail: [email protected]

Abstract

In the title compound, C19H16F3N3O2S, the side-chain carbonyl group, the adjacent double bond and the amine N atom are essentially coplanar, with the largest deviation from the mean plane being 0.010 (2) Å. A strong intramolecular N—H⋯O hydrogen bond [N⋯O 2.702 (3) Å and N—H⋯O 139 (3)°] is observed, leading to an en­amine tautomer in the solid state.

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