Volume 58, Issue 3 pp. o259-o260

2,3,5-Tri­chloro-6-(2-diethyl­amino­vinyl)-1,4-benzo­quinone

Alexander Krivokapic

Alexander Krivokapic

University of Oxford, Department of Chemistry, Dyson Perrins Laboratory, South Parks Road, Oxford OX1 3QY, England

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Harry L. Anderson

Harry L. Anderson

University of Oxford, Department of Chemistry, Dyson Perrins Laboratory, South Parks Road, Oxford OX1 3QY, England

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First published: 29 July 2004
Alexander Krivokapic, e-mail: [email protected]

Abstract

We report the structure of the title compound, C12H12Cl3NO2, which belongs to a group of compounds called blue quinones. It is a remarkable near-IR dye with interest for non-linear optics. It crystallized in monoclinic space group P21/a with one mol­ecule in the asymmetric unit. The molecular structure is approximately planar and exhibits little bond-length alternation, indicating a high degree of charge-transfer from the amine lone pair to the quinone.

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